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2002 | 05 | 2 |

Tytuł artykułu

Evaluation of adsorption parameters and charge densities of some selected soils: application to lead

Autorzy

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
An attempt to evaluate adsorption parameters and charge-based densities for Pb is reported in the paper. The method was based on the calculation of Langmuir adsorption maximum (amax), and the bonding energy term (b). The parameters were the outcome of well-established linear relationships of Ce/S versus Ce (Ce, equilibrium concentration and S, amount adsorbed). The use of charge-based sorption density parameter (SDCEC), which expressed the number of accessible charges for Pb adsorption, evidenced the occurrence of two main adsorption phases, characterised by two different slopes. The first ones, varying from 0.536 to 3.144 were suggested to be attributed to ‘high attractive sites’, whereas the second with slopes from 0.011 to 0.259, probably represented ‘low attractive sites.

Wydawca

-

Rocznik

Tom

05

Numer

2

Opis fizyczny

http://www.ejpau.media.pl/series/volume5/issue2/environment/art-03.html

Twórcy

autor
  • Agricultural University of Poznan, Wojska Polskiego 71F, 60-625 Poznan, Poland

Bibliografia

  • Carter D. L., Mortland M. M., Kemper W. D.: Specific surface. In “Methods of Soils Analysis, Part I – Physical and Mineralogical Methods” (A. Klute, ed.) 2nd ed.; pp. 413-423. Am. Soc. Agron., Madison, WI., 1986.
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  • Diatta J. B., Kocialkowski W.: Adsorption of zinc in some selected soils. Pol. J. Environ. Stud. 7(4):195-200, 1998.
  • Elkahatib E. A., Elshebiny G. M. Elsubruiti G. M. and M. A. Balba: Thermodynamics of lead sorption and desorption in soils. Z. Pflanzenernahr, Bodenk., 156:461-465, 1993.
  • Gao S., Walker W. J., Dahlgren R. A., Bold J.: Simultaneous sorption of Cd, Cu, Ni, Zn, Pb, and Cr on soils treated with sewage sludge supernatant. Wat., Air and Soil Poll., 93:331-345, 1997.
  • Giles C. H., McEwan T. H., Nakhawa S. N., and Smith D.: Studies in adsorption. Part XI. A system of classification of solution adsorption isotherms, and its use in diagnosis of adsorption mechanisms and in measurement of specific surface areas of solids. J. Chem. Soc., 3973-93, 1960.
  • Harter R. D : Curve-fit errors in Langmuir adsorption maxima. Soil Sci. Soc. Am J., 48: 749-752, 1984.
  • Helios-Rybicka E., Calmano W. and Breeger A: Heavy metals sorption/desorption on competing clay minerals; an experimental study. Appl. Clay Sci., 9:369-381, 1995.
  • IUNG: Assessment of degree of heavy metals and sulphur contamination in soils and plants [Ocena stopnia zanieczyszczenia gleb i roslin metalami ciezkimi i siarka]. Pulawy, p. 20, 1993.
  • Kocialkowski W. Z., Ratajczak M. J.: A simplified Mehlich method for determining exchangeable cations and cation exchange capacity of soils [Uproszczona metoda oznaczania kationow wymiennych oraz pojemnosci wymiennej w stosunku do kationow gleby wedlug Mehlicha]. Rocz. AR- Poznań; CXLVI, 106-116, 1984.
  • Lindsay W. L., and Norvell W. A.: Development of a DTPA soil test for zinc, iron, manganese and copper. Soil Sci. Soc. Am. J., 42:421-428, 1978.
  • Litynski T. Jurkowska H., and Gorlach E.: Agrochemical analysis. Methodical guide for soils and fertilizers’ analysis [Analiza chemiczno-rolnicza. Przewodnik metodyczny do analizy gleb i nawozow. PWN, Warszawa]. PWN, Warszawa, 1976.
  • Msaky J. J. and Calvet R. (1990): Adsorption behaviour of copper and zinc in soils: Influence of pH on adsorption characteristics. Soil Sci., 150(2):513-522.
  • Polish Standard: Polish Standarisation Committee, ref. PrPN-ISO 10390 (E), Soil quality and pH determination [Jakosc gleby i oznaczanie pH]. First edition [Pierwsze wydanie], 1994.
  • Salim I. A., Miller C. J., Howard J. J.: Sorption isotherm-sequential extraction analysis of heavy metal retention in landfill liners. Soil Sci. Soc. Am. J., 60:107-114, 1996.
  • Santillan-Medrano J. and Jurinak J. J.: The chemistry of lead and cadmium in soil: solid phase formation. Soil Sci. Soc. Am. Proc., 39:851-856, 1975.
  • Sauerbeck D., Lubben S.: Okologie ein Forderschwerpunkt des BMFT, band 6/1991. ISBN 3-89336 - 081 – 6, 1991.
  • Schulte A. and Beese F.: Isotherms of cadmium sorption density. J. Environ. Qual. 712-718, 1994.
  • Soil Survey Division Staff: Soil Survey Manual. USDA, Handbook Np. 18, 1994.
  • Sokołowska Z. (1989): Role of surface heterogeneity on adsorption processes in soils [Rola niejednorodnosci powierzchni w procesach adsorpcji zachodzacych na glebach.] Agrophysical Issues [Problemy Agrofizyki], 58:1-170.
  • Sposito G., Holtzclaw K. M. and LeVesque-Madore C. S.: Cupric ion complexation by fulvic acid extracted from sewage sludge-soil mixtures Soil Sci. Soc. Am. J. 43, 1148-1155, 1979.
  • Sposito G.: The surface chemistry of soils. Oxford Univ. Press. New York, 1984.
  • Wu J., Laird D. A. and Thompson M. L. (1999): Sorption and desorption of copper on soil clay components. J. Environ. Qual. 29(1):334-338.
  • Zehetner F. and Wenzel W.W.: Nickel and copper sorption in acid forest soils. Soil Sci. 165 (6):463-472, 2000.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

bwmeta1.element.agro-article-a95d3293-ca17-4ecb-8568-93e267cf09e4
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