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2009 | 18 | 3 |

Tytuł artykułu

Nanofiltration of cork wastewaters and their possible use in leather industry as tanning agents

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
Cork processing wastewater is a very complex mixture of vegetal extracts and has, among other natural compounds, a very high content of phenolic/tannic colloidal matter that is responsible for severe environmental problems. In the present work, the concentration of this wastewater by nanofiltration was investigated with the aim of producing a cork tannin concentrate to be utilized in tanning. Permeation results showed that the permeate fluxes are controlled by both osmotic pressure and fouling/gel layer phenomena, leading to a rapid decrease of permeate fluxes with the concentration factor. The rejection coefficients to organic matter were higher than 95%, indicating that nanofiltration has a very good ability to concentrate the tannins and produce a permeate stream depleted from organic matter. The cork tannin concentrate obtained by nanofiltration and evaporation had total solids concentration of 34.8 g/l. The skins tanned by this concentrate were effectively converted to leather with a shrinking temperature of 71℃ .

Wydawca

-

Rocznik

Tom

18

Numer

3

Opis fizyczny

p.353-357,fig.,ref.

Twórcy

autor
  • Department of Chemical and Biological Engineering, Instituto Superior Técnico, Technical University of Lisbon, Av. Rovisco Pais 1, 1049-001 Lisbon, Portugal
autor
  • Department of Chemical Engineering, Instituto Superior de Engenharia de Lisboa, Rua Conselheiro Emídio Navarro 1, 1959-007 Lisbon, Portugal
autor
  • Department of Chemical and Biological Engineering, Instituto Superior Técnico, Technical University of Lisbon, Av. Rovisco Pais 1, 1049-001 Lisbon, Portugal
autor
  • Leather Engineering Department, Engineering Faculty, Ege University, 35100 Izmir, Turkey
autor
  • Leather Engineering Department, Engineering Faculty, Ege University, 35100 Izmir, Turkey
autor
  • Leather Engineering Department, Engineering Faculty, Ege University, 35100 Izmir, Turkey
autor
  • Leather Engineering Department, Engineering Faculty, Ege University, 35100 Izmir, Turkey

Bibliografia

  • 1. KÖRBAHTI B. ve ark. Investigation of polymeric materials obtained from electrochemical oxidation of phenol containing wastewaters. 2000’li Yıllarda Şehir ve Sanayide Atıklar ve Arıtımı Uluslararası Sempozyumu ve Sergisi, 17-20 Mayıs, Istanbul, 2001 [In Turkish]. 2. SONG Z., WILLIAMS C.J., EDYVEAN R.G.J. Sedimentation of tannery wastewater. Water Research, 34(7), 2171, 2000.
  • 3. SHARLI A., MADHAN B., RAGHAVA RAO J., UNNINAIR B. An approach for the treatment of vegetable tan liquor containing hydrolysable tannins. Journal of the Society of Leather Technologists and Chemists, 98(10), 381, 2003.
  • 4. SUOMINEN K., KITUNEN V., SMOLANDER A. Characteristics of dissolved organic matter and phenolic compounds in forest soils under silver brich (Betula pendula), Norway Spruce (Picea abies) and Scots Pine (Pinus sylvestris). European Journal of Soil Science, 54, 284, 2003.
  • 5. ALKAN A., SENGUL F. Treatment of phenol containing wastewaters by chemical oxidation. D.E.U. Muhendislik Mimarlik Fakultesi Cevre Muhendisigi Bolumu, Diploma Tezi, pp. 3-17, 1990 [In Turkish].
  • 6. ACERO J.L., BENITEZ F.J., DE HEREDIA J.B., LEAL A.I. Chemical treatment of cork-processing wastewaters for potential reuse, Journal of Chemical Technology and Biotechnology, 79(10), 1065, 2004.
  • 7. ACERO J.L., BENITEZ F.J., REAL F.J., LEAL A.I., SORDO A. Oxidation of esculetin, a model pollutant present in cork processing wastewaters, by chemical methods. Ozone: Science and Engineering, 27(4), 317, 2005a.
  • 8. BENITEZ F.J., ACERO J.L., GARCIA J., LEAL A.I. Purification of cork processing wastewaters by ozone, by activated sludge, and by their two sequential applications, Water Research, 37(17), 4081, 2003.
  • 9. BENITEZ F.J., REAL F.J., ACERO J.L., LEAL A.I., GARCIA C. Gallic acid degradation in aqueous solutions by UV/H2O2 treatment, Fenton's reagent and the photo-Fenton system, Journal of Hazardous Materials, 126(1-3), 31, 2005a.
  • 10. BENITEZ F.J., REAL F.J., ACERO J.L., LEAL A.I., COTILLA S. Oxidation of acetovanillone by photochemical processes and hydroxyl radicals, Journal of Environmental Science and Health - Part A Toxic/Hazardous Substances and Environmental Engineering, 40(12), 2153, 2005b.
  • 11. GUEDES A.M.F.M., MADEIRA L.M.P., BOAVENTURA R.A.R., COSTA C.A.V. Fenton oxidation of cork cooking wastewater - Overall kinetic analysis, Water Research, 37(13), 3061, 2003.
  • 12. PERES J.A., De HEREDIA J. B., DOMÍNGUEZ J.R. Integrated Fenton's reagent- Coagulation/flocculation process for the treatment of cork processing wastewaters, Journal of Hazardous Materials, 107(3), 115, 2004.
  • 13. DOMÍNGUEZ J.R., De HEREDIA J.B., GONZÁLEZ T., SANCHEZ-LAVADO F., Evaluation of ferric chloride as a coagulant for cork processing wastewaters. Influence of the operating conditions on the removal of organic matter and settle ability parameters, Industrial and Engineering Chemistry Research, 44(17), 6539, 2005.
  • 14. MENDONCA E., PEREIRA P., MARTINS A., ANSELMO A.M. Fungal biodegradation and detoxification of cork boiling wastewaters, Engineering in Life Sciences, 4(2), 144, 2004.
  • 15. CIESLA, W. M. Non-wood forest products from temperate broad-leaved trees: Non-Wood Forest Products 15, Food and Agriculture Organization of the United Nations, Rome, 2002.
  • 16. MINHALMA M., DIAS C. R., De PINHO, M.N. Membrane fouling in ultrafiltration of cork processing wastewaters, Advances in Environmental Research, 3(4), 539, 2000.
  • 17. MINHALMA M., De PINHO M.N. Tannic-membrane interactions on ultrafiltration of cork processing wastewaters, Separation and Purification Technology, 22-23, 479, 2001a.
  • 18. MINHALMA M., De PINHO M.N. Flocculation/flotation/ultrafiltration integrated process for the treatment of cork processing wastewaters, Environmental Science and Technology, 35, 4916, 2001b.
  • 19. MINHALMA M., DOMÍNGUEZ J.R., De PINHO, M.N. Cork processing wastewaters treatment by an ozonization/ultra filtration integrated process, Desalination, 191, 148, 2006.
  • 20. ACERO J.L., BENÍTEZ F.J., LEAL A.I., REAL F.J. Removal of phenolic compounds in water by ultra filtration membrane treatments, Journal of Environmental Science and Health-Part A Toxic/Hazardous Substances and Environmental Engineering, 40(8), 1585, 2005b.
  • 21. GERALDES V., De PINHO M.N. Mass transfer coefficient determination method for high-recovery pressure-driven membrane modules, Desalination, 195, 69, 2006.
  • 22. Official Methods of Analysis of the Society of Leather Technologists and Chemists, 1996.
  • 23. Pocket Book for the Leather Technologist, ed. by BASF Aktiengesellschaft Ludwigshafen, Germany, pp. 87, 1996.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

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