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2007 | 16 | 4 |

Tytuł artykułu

Determination of PCBs in selected components of a food chain by means of SPE and GC-MS

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
The goal of this work was the isolation of PCBs from different environmental matrices by means of solid-phase (SPE) extraction and gas chromatography/mass spectrometry (GC/MS). The analyses include the determination of PCBs in fourteen samples of transformer oils and different kinds of fodders (for poul­try, pigs, and cattle). The recovery rates for different congeners were on the level of 75-85%. The detec­tion limits of five congeners of PCBs were in the range 85 to 130 ug/kg. The RSD was on the level of 2.7 - 4.4%. The Ishikawa diagram was used for evaluation of uncertainty.

Wydawca

-

Rocznik

Tom

16

Numer

4

Opis fizyczny

p.571-578,fig.,ref.

Twórcy

autor
  • Nicolaus Copernicus University, 7 Gagarina St., 87-100 Torun, Poland
autor
autor

Bibliografia

  • 1. GOMEZ J.L., BUJALANCE M., GIRALDEZ I., VELASCO A., ORALES E. M. Determination of PCB in biota samples using simultaneous pressurized liquid extraction and purifi­cation. J. Chormatogr. A, 946, 209, 2002.
  • 2. BORDAJANDI L.R., GOMEZ G., FERNANDEZ M.A., ABAD E., RIVERA J., GONZALEZ M. Study on PCBs, PCDD/Fs, organochlorine pesticides, heavy metals and ar­senic content in fresh water fish species from the River Turia (Spain). Chemosphere 53, 163, 2003.
  • 3. ROSS G. The public health implications of polychlorinated biphenyls (PCBs) in the environment. Ecotoxicology and Environmental Safety, 59, 275, 2004.
  • 4. VOOGT P., WELLS D.E., RAUTERGARDH L., BRINK- MAN U.A.Th. Biological activity, determination and oc­curence of planar, mono- and diortho PCBs. Intern. J. Envi­ron. Anal. Chem., 40, 1, 1990.
  • 5. SAUVIN J.J., DE ALENCASTRO L.F., TARRADELLAS J., CAMENZIND R., KARLAGANIS G., VUILLEUMIER C. Comparison of four quantification methods for the de­termination of PCB in transformer oils. Fresenius J. Anal. Chem., 350, 555, 1994.
  • 6. LULEK J. Levels of polychlorinated biphenyls in some waste motor and transformer oil from Poland. Chemosphere, 37, 2021, 1998.
  • 7. KOCAN A., PETRIK J., JURSA S., CHOVANCOWA J., DROBNA B. Environmental contamination with polychlorinated biphenyls in the area of their form manufacture in Slovakia. Chemosphere, 43, 595, 2001.
  • 8. SCHANTZ S. L. Developmental neurotoxicity of PCBs in humans: What do we know and where do we go from here? Neurotoxicology and Teratology, 18, 217, 1999.
  • 9. ABAD E., LLERENA J.J., SAULO J., CAIXACH J., RI­VERA J. Study on PCDDs/PCDFs and co-PCBs content in food samples from Catalonia (Spain). Chemosphere, 46, 1435, 2002.
  • 10. GOMARA B., FERNANDEZ M.A., GONZALES M.J., RAMOS L. J. Feasibility of gas chromatography-ion trap tandem mass spectrometry for the determination of poly- chlorinated biphenyls in food. Int. J. Sep. Sci., 29, 123, 2006.
  • 11. EN 1528-1, Fatty Food. Determination of Pesticides and PCB. General, Beuth Verlag, Berlin 1997.
  • 12. EN 1528-3, Fatty Food. Determination of Pesticides and PCB, Clean-up Methods, Beuth Verlag, Berlin 1997.
  • 13. SPARR C., BJORKLUND E. Analytical-scale microwave- assisted extraction. J. Chromatogr. A, 902, 227, 2000.
  • 14. VETTER W., WEICHBRODT M., HUMMERT K., GLOTZ D. , LUCKAS B., Combined microwave-assisted extraction and gel permeation chromatography for the determination of chlorinated hydrocarbons in seal blubber and cod livers. Chemosphere, 37, 2439, 1998.
  • 15. HAWTHORNE S.B. Analytical-scale supercritical fluid ex­traction. Anal. Chem., 62, 633A, 1990.
  • 16. SMITH R.M. Supercritical fluids in separation science-the dreams, the reality and the future. J. Chromatogr. A, 856, 83, 1999.
  • 17. RICHTER B.E., JONES B.A., EZELLI J. L., PORTER N.L., AVDALOVIC N., POHL C. Accelerated solvent extraction: a technique for sample preparation. Anal. Chem., 68, 1033, 1996.
  • 18. MAJORS R.E. An overview of sample preparation. LC-GC Int., 4.10, 1991.
  • 19. JUAN C.Y., THOMAS G.O., SEMPLE K.T., JONES K.C. Methods for the analysis of PCBs in human food, faeces and serum. Chemosphere, 39, 1467, 1999
  • 20. LOVETT A.A., FOXAL C.D., CREASER C.S., CHEWE D. PCB and PCDD/DF congeners in locally grown fruit and vegetable samples in wales and England. Chemosphere, 34, 1421, 1997.
  • 21. WELLS D.E., MAIER B., GRIEPINK B. Calibrants and calibration for chlorobiphenyl analysis. Inter. J. Anal. Chem., 46, 255, 1992.
  • 22. JUAN C.Y., THOMAS G.O., SEMPLE K.T., JONES K.C. Methods for determination of PCBs in human food, faeces and serum. Chemosphere, 39, 1467, 1999.
  • 23. FRAME G.M. A collaborative study of 209 PCB congeners and 6 Aroclors on 200 different HRGC columns. Fresenius J. Anal. Chem., 357, 714, 1997.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

bwmeta1.element.agro-article-93b20e62-3276-418f-bdca-cda3af5fc618
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