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2005 | 14 | 3 |

Tytuł artykułu

Fractionation of some heavy metals in bottom sediments from the Middle Odra River [Germany-Poland]

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
Fractionation of Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn has been performed in bottom sediment samples collected along a 75 km section of the middle Odra River by a modified method of 5-step sequential extraction according to Tessier. The results have shown the presence of Cu, Ni, Zn and Mn already in exchange fraction (I); the mean percent content of metals in mobile phases (exchange and carbonate) reached 35% (Cu), while the maximum values reached 59% (Ni). From among the metals studied, Zn, Mn, Fe, Cr and Ni were dominant in the species bound to hydrated iron and manganese oxides, so the metals contained in the bottom sediments were not permanently immobilized. Good correlation was found between the concentrations of Zn, Mn and Cd in the mobile phases (I+II) and their total concentrations. Similarly, the concentrations of all metals determined in the reducible fraction and in the fraction bound to organic matter (except for Cd and Cr) were well correlated to their total content.

Wydawca

-

Rocznik

Tom

14

Numer

3

Opis fizyczny

p.305-317,fig,ref

Twórcy

autor
  • A.Mickiewicz University, Kosciuszki 1, 69-100 Slubice, Poland
autor
autor
autor

Bibliografia

  • 1. RAST G., OBRDLIK P., NIEZNAŃSKI P. (Eds.) Atlas of the Odra floodplains. WWF Deutschland/WWF-Auen-Institut, 2000.
  • 2. State of the Environment in the Lubuskie Province in 2000. Voivodship Environmental Protection Inspectorate (WIOS), Zielona Góra – Gorzów Wlkp. 2001. (In Polish)
  • 3. BEHRENDT H., DANNOWSKI R., DEUMLICH D., DOLEZAL., KAJEWSKI I., KORNMILCH M., KOROL R., MIODUSZEWSKI W., OPITZ D., STEIDL J., STRONSKA M. Investigation the quantity of diffuse entries in the rivers of the catchment area of the Odra and the Pomeranian Bay to develop decision facilities for an integrated approach on waters protection (Phase III). Final report, Institute of Freshwater Ecology and Inland Fisheries, Berlin, pp. 271, 2002.
  • 4. VINK R., BEHRENDT H. Heavy metal transport in large river systems: heavy metal emissions and loads in the Rhine and Elbe River basins. Hydrol. Process., 16, 3227, 2002.
  • 5. NIEMIRYCZ E. The pollution load from the Odra River in comparison to that in other polish rivers in 1988-1997. Acta Hydroch. Hydrob., 27, 286, 1999.
  • 6. QUEVAUVILLER PH. SM&T Activities in Support of standardisation of operationally-defined extraction procedures for soil and sediment analysis. In: Quevauviller Ph. (Eds.) Methodologies for soil and sediment fractionation studies. The Royal Society of Chemistry, pp. 1-9, 2002.
  • 7. BERNHARD T., NEFF J. Metals bioavailability in the Navy’s tiered ecological risk assessment process. Naval Facilities Engineering Command. Issue Papers, 1-15, (http://web. ead.anl.gov/ecorisk/issue), 2001.
  • 8. TESSIER A., CAMPBELL P.G., BISSON M. Sequential extraction procedure for the speciation of particulate trace metals. Anal. Chem., 51, 844, 1979.
  • 9. NAMIEŚNIK J., JAMRÓGIEWICZ Z., PILARCZYK M., TORRES L. Preparation of the environmental samples for analysis. Scientific and Technical Publishers (WNT), pp. 176, Warszawa, 2000. (In Polish)
  • 10. HLAVAY J., PROHASKA T., WEISZ M., WENZEL W.W., STINGEDER G.J., Determination of trace elements bound to soils and sediment fractions, (IUPAC Technical Report). Pure Appl. Chem., 76(2), 415, 2004.
  • 11. SOBCZYŃSKI T., SIEPAK J., Methodological aspects of sequential extraction of metals occurring in bottom sediments. In: Communal Waste Management. Proceedings of the 7th Scientific-Technical Conference, Koszalin-Kołobrzeg, pp. 312-221, 2001. (In Polish)
  • 12. BOSZKE L., SOBCZYŃSKI T., GŁOSIŃSKA G., KOWALSKI A., SIEPAK J., Distribution of Mercury and Other Heavy Metals in Bottom Sediments of the Middle Odra River (Germany/Poland). Pol. J. Environ. Stud.13, 495, 2004.
  • 13. HELIOS-RYBICKA E., SIKORA W. S., WÓJCIK R., WARDAS M., STRZEBOŃSKA M., ADAMIEC E., ŁAGAN Ł. Estimation of pollution by heavy metals of bottom sediments in the Upper and Middle Odra River. Gospodarka Wodna, 60, 300, 2000. (In Polish)
  • 14. GONZALEZ A. E., RODRIGUEZ M.T., SANCHEZ J.C.J., ESPINOSA A.J.F., De La ROSA F.J.B., Assessment of metals in sediments in a tributary of the Guadalquivir River (Spain). Heavy metal partitioning and relation between the water and sediment system. Water Air Soil Poll., 121, 11, 2000.
  • 15. BUYKX S.E.J., BLEIJENBERG M., van den HOOP M.A.G.T., LOCH J.P.G., The effect of oxidation and acidification on the speciation of heavy metals in sulfide-rich freshwater sediments using a sequential extraction procedure. J. Environ. Monit., 2, 23, 2000.
  • 16. KLAVINS M., BRIEDE A., RODINOV V., KOKORITE I., PARELE E., KLAVINA I., Heavy metals in rivers of Latvia. Sci. Total Environ., 262, 175, 2000.
  • 17. LICHENG Z., GUIJIU Z. The species and geochemical characteristics of heavy metals in the sediments of Kangjiaxi River in the Shuikoushan Mine Area, China. Appl. Geochem., 11, 217, 1996.
  • 18. KUANG-CHUNG YU, LI-JYUR TSAI, SHIH-HSIUNG CHEN, SHIEN-TSONG HO. Correlation analyses on binding behaviour of heavy metals with sediment matrices. Wat. Res. 35, 2417, 2001.
  • 19. BORDAS F., BOURG A.C.M., A critical evaluation of sample pre-treatment for storage of contaminated sediments to be investigated for the potential mobility of their heavy metal load. Water Air Soil Poll., 103, 137, 1998.
  • 20. ADAMIEC E., HELIOS-RYBICKA E. Distribution of pollutants in the Odra River System Part V. Assessment of Total and Mobile Heavy Metals Content in the Suspended Matter and Sediments of the Odra River System and Recommendations for River Chemical Monitoring. Pol. J. Environ. Stud., 11, 675, 2002.
  • 21. SVETE P., MILACIC R., PIHLAR B., Partitioning of Zn, Pb, Cd in river sediments from a lead and zinc mining area using the BCR three-step sequential extraction procedure. J. Environ. Monit., 3, 586, 2001.
  • 22. QUEVAUVILLER PH., RAURET J.F., LOPEZ-SANCHEZ J.F., RUBIO R., URE A., MUNTAU H., Certification of trace metals extractable contents in a sediment reference material CRM (601) following a three step sequential extraction procedure. Sci. Total Environ., 205(2-3), 223, 1997.
  • 23. MORILLO J., USERO J., GRACIA I., Partitioning of metals in sediments from the Odiel River (Spain). Environ. Int., 28, 263, 2002.
  • 24. HYK W., STOJEK Z., Statistical analysis in analytical laboratory. Analytical Chemistry Committee of Polish Academy of Sciences, Warszawa, pp. 92, 2000. (In Polish)
  • 25. VAITHIYANATHAN P., RAMANATHAN A., SUBRAMANIAN V. Transport and distribution of heavy metals in Cauvery River. Water Air Soil Poll., 71, 13, 1993.
  • 26. BOROVEC Z. Evaluation of the concentrations of trace elements in stream sediments by factor and cluster analysis and the sequential extraction procedure. Sci. Total Environ., 177, 237, 1996.
  • 27. IOP – International Odra Project. Results of International Odra Project. Meyer A.-K (eds.), Hamburg, pp. 127, 2002.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

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