Application of physicochemically modified polymeric foil to develop antioxidant packaging

• Autorzy: Trzcinska M. , Sieliwanowicz B. , Halasinska A.G. , Czuprynski B.

Warianty tytułu

PL

Wykorzystanie modyfikowanej fizyko-chemicznie folii polimerowej do opracowania opakowan o wlasciwosciach przeciwutleniajacych

• Języki publikacji: EN

Abstrakty

EN

The method of propyl gallate immobilization on the surface of polymeric film has been developed. Surface of polyethylene foil was modified by electric corona and coated with a chitosan layer prepared from 1% solution of polysaccharide dissolved in 1% lactic acid. Then, it was gelated in a mixture of ethanol and NaOH solution. A portion of gallate ranging from 2.87 to 5.67 μg/cm2 was immobilized in the coating prepared with the sorption method. The film obtained was characterised by antioxidant activity measured by scavenging DPPH• radicals and its mean value was equal to 9 × 10-3 TE/cm2. Preliminary measurements showed that the obtained polyethylene film coated with the chitosan layer containing immobilized propyl gallate lost half of its activity after about 5 months of storage at room temperature.

PL

Opracowano metodę unieruchomienia galusanu propylu na powierzchni folii polietylenowa pokrytej powłoką chitozanową. W utrwalonej w etanolu i NaOH warstwie, utworzonej z rozpuszczonego w 1% kwasie mlekowym chitozanu, naniesionej na modyfikowaną wyładowaniami elektrycznymi powierzchnię folii polietylenowej, unieruchomiono galusan propylu. Ze względu na korzystne właściwości fizykochemiczne przy konstruowaniu powłoki chitozanowej na powierzchni folii polietylenowej użyto roztworu chitozanu w kwasie mlekowym. Metodą sorpcyjną, w zależności od wyjściowego stężenia roztworu, unieruchamiano od 2.87 do 5.67 μg galusanu propylu/cm2 folii (tab. 1). Uzyskano folie wykazującą aktywność przeciwutleniającą, mierzoną w reakcji rodnikowej z DPPH, wynoszącą około 9 × 10-3 TE/cm2 (tab. 2). Wstępne pomiary wykazały, że folia polietylenowa pokryta chitozanem z unieruchomionym galusanem propylu traciła połowę aktywności po około 5 miesięcznym okresie przechowywania w temperaturze pokojowej (tab. 3).

Słowa kluczowe

EN

antioxidant packaging; development; physicochemically modified polymeric foil; application; polyethylene foil; functional packaging

• Wydawca: -
• Czasopismo: Polish Journal of Food and Nutrition Sciences
• Rocznik: 2007
• Tom: 57
• Numer: 2
• Opis fizyczny: p.173-176,ref.

Twórcy

autor

Trzcinska M.

• Institute of Biotechnology of Food and Agricultural Industry, Warsaw-Bydgoszcz, Poland

autor

Sieliwanowicz B.

autor

Halasinska A.G.

autor

Czuprynski B.

Bibliografia

• 1. Appendini P., Hotchkiss J.H., Review of antimicrobial food packaging. Innov. Food Sci. Emerg. Technol., 2002, 3, 113–126.
• 2. Barreiro-Iglesias R., Corronilla R., Concheiro A., Alvarez--Lorenzo C., Preparation of chitosan beads by simultaneous cross-linking/insolubilisation in basic pH. Rheological optimization and drug loading/release behaviour. Eur. J. Pharm. Sci., 2005, 24, 77–84.
• 3. Begin A., Van Calsteren M.R., Antimicrobial films produced from chitosan. Int. J. Biol. Macromol., 1999, 26, 63–67.
• 4. Cagri A., Ustunol Z., Ryser E.T., Antimicrobial edible films and coatings. J. Food Prot., 2004, 67, 833–848.
• 5. Cha D.S., Chinnan M.S., Biopolymer-based antimicrobial packaging: a review. Crit. Rev. Food Sci. Nutr., 2004, 44, 223–237.
• 6. Charles F., Rugani N., Gontard N., Influence of packaging conditions on natural microbial population growth of endive. J. Food Prot., 2005, 68, 1020–1025.
• 7. Coma V., Deschamps A., Martial Gros A., Bioactive packaging materials from edible chitosan polymer-antimicrobial activity assessment on dairy-related contaminants. J. Food Sci., 2003, 68, 2788–2792.
• 8. Del Nobile M.A., Pierogiovanni L., Buonocore G.G., Fava P., Puglisi M.L., Nicolais L., Naringinase immobilization in polymeric films intended for food packaging applications. J. Food Sci., 2003, 68, 2046–2049.
• 9. Dini E., Alexandridou S., Kiparissides C., Synthesis and characterization of cross-linked chitosan microspheres for drug delivery applications. J. Microencapsul., 2003, 20, 375–385.
• 10. Fernandez-Alvarez M., Active food packaging. Food Sci. Technol. Int., 2000, 6, 97–108.
• 11. Garde J.A., Catala R., Gavara R., Hernandez R.J., Characterizing the migration of antioxidants from polypropylene into fatty food stimulants. Food Addit. Contam., 2001, 18, 750–762.
• 12. Hodgson S.C., Casey R.J., Bigger S.W., Review of zeolites and deodorans polyethylene resins used in food packaging applications. Polym. Plast. Technol. Eng., 2002, 41, 795–818.
• 13. Kim D.O., Lee K.W., Lee H. J., Lee C.Y., Vitamin C equivalent antioxidant capacity (VCEAC) of phenolic phytochemicals. J. Agric. Food. Chem., 2002, 50, 3713–3717.
• 14. Krakowiak A., Trzcińska M., Sieliwanowicz B., Sawicka- -Żukowska R., Jędrychowska B., Ajzenberg V., Properties of immobilized and free lipase from Rhizopus cohnii. Pol. J. Food Nutr. Sci., 2003, 12/53, 3, 39–44.
• 15. Kruijf de N., van Beest M., Rijk R., Sipilainen-Malm T., Paseiro Losada P., De Meulenaer B., Active and intelligent packaging: applications and regulatory aspects. Food Addit. Contam., 2002, 19 Suppl., 144–162.
• 16. Leffler C.C., Muller B.W., Influence of the acid type on the physical and drug liberation properties of chitosan-gelatin sponges. Int. J. Pharm., 2000, 194, 229–237.
• 17. Maloba F.W., Rooney M.L., Wormell P., Nguyen M., Improved oxidative stability of sunflower oil in the presence of an oxygen- -scavenging film. J. Am. Oil Chem. Soc., 1996, 73, 181–185.
• 18. Moller H., Grelier S., Pardon P., Coma V, Antimicrobial and physicochemical properties of chitosan-HPMC-bassed films. J. Agric. Food Chem., 2004, 52, 6585–6591.
• 19. Oussalah M., Caillet S., Salmieri S., Saucier L., Lacroix M., Antimicrobial and antioxidant effects of milk protein-based film containing essential oils for the preservation of whole beef muscle. J. Agric. Food Chem., 2004, 52, 5598–5605
• 20. Ouattar B., Simard R.E., Piett G., Begin A., Holley R.A., Inhibition of surface spoilage bacteria in processed meats by application of antimicrobial films prepared with chitosan. Int. J. Food Microbiol., 2000, 62, 139–148.
• 21. Ozdemir M., Floros J.D., Active food packaging technologies. Crit. Rev. Food Sci. Nutr., 2004, 44, 185–193.
• 22. Park S.I., Zhao Y., Incorporation of a high concentration of mineral or vitamin into chitosan-based films. J. Agric. Food Chem., 2004, 52, 1933–1939.
• 23. Peh K., Khan T., Ch’ng H., Mechanical, bioadhesive strength and biological evaluations of chitosan films for wound dressing. J. Pharm. Pharm. Sci., 2000, 3, 303–311.
• 24. Rhoades J., Roller S., Antimicrobial actions of degraded and native chitosan against spoilage organisms in laboratory media and foods. Appl. Environ. Microbiol., 2000, 66, 80–86.
• 25. Shin H.S., Lee Y., Antioxidant impregnated food packaging materials film inhibition of lipid oxidation. Food Sci. Biotechnol., 2003, 12, 737–746.
• 26. Sieliwanowicz B., Komorowska A., Jędrzejczak R., Adsorption of iron by polyphosphate derivatives of chitin and chitosan. Pol. J. Food Nutr. Sci., 1995, 4/45, 1, 53–59.
• 27. Suppakul P., Miltz J., Sonneveld K., Bigger S.W., Active packaging technologies with an emphasis on antimicrobial packaging and its applications. J. Food Sci., 2003, 68, 408–420.
• 28. Tovar L., Salafranca J., Sanchez C., Nerin C., Migration studies to assess the safety in use of a new antioxidant active packaging. J. Agric. Food Chem., 2005, 53, 5270–5275.
• 29. Trzcińska M., b-Glucosidase from Aspergillus niger 33/20/K. Isolation, properties, potential application. Habilitation thesis, Acta Acad. Agricult. Tech. Olst. Technologia Alimentorum, 1998, 29, Supplementum B, pp. 35–41 (in Polish).
• 30. Veremiren L., Develieghere F., Debevere J., Effectiveness of some recent antimicrobial packaging concepts. Food Addit. Contam., 2002, 19 Suppl., 163–171.
• 31. Wu Y., Weller C.L., Hamouz F., Cuppett S.L., Schnepf M., Development and application of multicomponent edible coatings and films: a review. Adv. Food Nutr. Res., 2002, 44, 347–394.
• 32. Żenkiewicz M., Adhezja i modyfikowanie warstwy wierzchniej tworzyw wielkocząsteczkowych. WNT, Warszawa, 2000, pp. 171–184 (in Polish).