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2005 | 08 | 2 |

Tytuł artykułu

The changes in the internal structure of starch granules caused by oxidation

Autorzy

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
Native starches, such as potato, wheat, maize, and waxy maize, were subject to oxidation with sodium chlorate(I), hydrogen peroxide in the presence of Cu2+ ions, and sodium chlorate(III) in the presence of formaldehyde. Native starches and their modified preparations were determined for the content of carboxyl and aldehyde groups. In order to determine changes in the internal structure of starch granules, thermodynamic characterization of phase transitions (DSC) was taken and the degree of crystallinity with X-ray diffractions was determined. Potato starch, after oxidation with the applied reagents, became slightly more crystalline, while cereal starches were affected very little. The thermodynamic gelatinization indices obtained for oxidized starches were only changed a small amount in comparison to native ones, which means that the internal structure of the granules is almost unaffected by oxidation.

Słowa kluczowe

Wydawca

-

Rocznik

Tom

08

Numer

2

Opis fizyczny

http://www.ejpau.media.pl/volume8/issue2/art-23.html

Twórcy

autor
  • Agricultural University of Krakow, Balicka 122, 30-149 Krakow, Poland

Bibliografia

  • Eliasson A. C., Karlsson R., 1983. Gelatinization properties of different size classes of wheat starch granules measured with differential scanning calorimetry. Starch/Stärke 35, 130-133.
  • Forsell P., Hamunen A., Autio K., Suorti T., Poutanen K., 1995. Hypochlorite oxidation of barley and potato starch. Starch/Stärke 47, 371-377.
  • Fortuna T., Juszczak L., Pietrzyk S., Wróbel M., 2002. Physico-chemical properties of oxidized starches of different origin. Pol. J. Food Nutr. Sci. 11/52, 21-27.
  • Fortuna T., Pietrzyk S., 2002. Comparison of physico-chemical properties of starches oxidized with sodium chlorite and hydrogen peroxide. Zesz. Probl. Post. Nauk Roln. 489, 401-413 [in Polish].
  • Fredriksson H., Silverio J., Andersson R., Eliasson A. C., Aman P., 1998. The influence of amylose and amylopectin characteristics on gelatinization and retrogradation properties of different starches. Carbohydr. Polym. 35, 119-134.
  • Hebeish A., El-Sisy F., Abdel-Hafiz S. A., Abdel-Rahman A. A.,
  • El-Rafie M. H., 1992. Oxidation of maize and rice starches using sodium chlorite along with formaldehyde. Starch/Stärke 44, 388-393.
  • Jane J., Kasemsuwan T., Chen J. F., Juliano B. O., 1996. Phosphorus in rice and other starches. Cereal Foods World , 41(11), 827-832.
  • Jane J., Wong K., McPherson A., 1997. Branch-structure difference in starches of A - and B - type X-ray patterns revealed by their Naegeli dextrins. Carbohydr. Res. 300, 219-227.
  • Kuakpetoon D., Wang Y. J., 2001. Characterization of different starches oxidized by ypochlorite. Starch/Stärke 53, 211-218.
  • Modified Starch - Determination of Carboxyl Group Content of Oxidized Starch.1996. ISO 11214.
  • Muhrbeck P., Eliasson A. C., Salomonsson A. C., 1990. Physical characterization of bromine oxidized potato starch. Starch/Stärke 42, 418-420.
  • Noda T., Takahata Y., Sato T., Suda I., Morishita T., Ishiguro K., Yamakawa O., 1998. Relationships between chain lenght distribution of amylopectin and gelanitization properties within the same botanical origin for sweet potato and buckwheat. Carbohydr. Polym. 37, 153-158.
  • Parovuori P., Hamunen A., Forsell P., Autio K., Poutanen K., 1995. Oxidation of potato starch by hydrogen peroxide. Starch/Stärke 47, 19-23.
  • Pietrzyk S., Fortuna T., 2005. Oxidation-induced changes in the surface structure of starch granules. Pol. J.Food Nutr. Sci. (in press).
  • Potze J., Hiemstra P., 1963. Über den einfluss der reaktionsbedngungen auf die oxydation der kartofflestärke mit hypochlorit. Starch/Stärke 15, 217-225 [in German].
  • Shi Y., Capitani T., Trzasko P., Jeffcoat R., 1998. Molecular structure of a low-amylopectin starch and other high-amylose maize starches. J. Cereal Sci. 27, 289-299.
  • Singh J., Singh N., 2001. Studies on the morphological, thermal and rheological properties af starch separated from some Indian potato cultivars. Food Chem. 75, 67-77.
  • Son Y., Jane J., 2000. Characterization of barley starches of waxy, normal, and high amylose varietes. Carbohydr. Polym. 41, 365-377.
  • Stevens D. J., Elton G. H. A., 1971. Albans St. Thermal properties of starch/water system. Part I. Measurment of heat of gelatinization by differential scanning calorimetry, 23, 8-11.
  • Veelaert S., Polling M., Wit D., 1994. Structural and physicochemical changes of potato starch along periodate oxidation. Starch/Stärke 46, 263-268.
  • Wang T., Ya T., Hedley B. C., 1998. Starch: as simple as A, B, C?. J. Exp. Bot. 49, 481-502.
  • Wootton M., Bamunuarachchi A., 1979. Application of differential scanning calorimetry to starch gelatinization. Starch/Stärke 23, 2-8.
  • Zhu Q., Bertoft E., 1997. Enzymatic analysis of the structure of oxidized potato starches. Int. J. Biol. Macromol. 21, 131-135.
  • Zhu Q., Sjoholm R., Nurmi K., Bertoft E., 1998. Structural characterization of oxidized potato starch. Carbohydr. Res. 309, 213-218.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

bwmeta1.element.agro-article-6b03eae9-d41e-4824-8b7c-a42e5f0b2e63
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