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2002 | 11 | 4 |

Tytuł artykułu

Biodegradation of fatty alcohol ethoxylates under the conditions of the die-away test

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
Oxyethylated alcohol ± surfactant C12E10 ± was tested under the conditions of the die-away test with activated sludge as inoculum. The residual surfactant and its biotransformation by-products: short-chained ethoxylates (SCE) and long-and short-chained poly(ethylene glycols) (PEG) were separated and determined using the indirect tensammetric technique. A high percentage of primary biodegradation (98.5%) and high concentration of SCE and PEG was found at the end of the experiment. There is a clear sequence of biotransformation: central fission ® fragmentation of the long-chained PEG into short-chained PEG. Generally, the same pathway was observed as in the case of oxyethylated alcohol biodegradation under the conditions of the continuous flow activated sludge test.

Wydawca

-

Rocznik

Tom

11

Numer

4

Opis fizyczny

p.429-433,fig.

Twórcy

autor
  • Poznan University of Technology, Piotrowo 3, 60-965 Poznan, Poland
autor
autor

Bibliografia

  • 1. BRUNNER P.H., CAPRI S, MARCOMINI A, GIGER W., Occurrence and Behaviour of Linear Alkylbenzenesulphon- ates, Nonylphenol, Nonylphenol Mono- and Nonylphenol Diethoxylates in Sewage and Sewage Sludge Treatment, Wat. Res., 22, 1465, 1988.
  • 2. FISCHER W.K., Entwicklung der Tensidkonzentrationen in den deutschen Gewassern 1960-1980, Tenside Deterg., 17, 250,1980.
  • 3. PALJCKA J., Development and Trends in the European Laundry Detergent Market, III International Symposium: Chemistry Forum'97', Warsaw, April, 1997.
  • 4. Information of Association of the Industry Producing Chemicals for Textile, Leather and Surfactant Plant TEGEWA, Germany, 2001.
  • 5. SZYMANSKI A., WYRWAS B., JESIOLOWSKA A., KAZ- MIERCZAK S., PRZYBYSZ T., GRODECKA J., LUKAS- ZEWSKI Z.. Surfactants in the River Warta: 1990-2000, Polish J.Environ. Studies, 10, 371, 2001.
  • 6. SZYMANSKI A, LUKASZEWSKI Z., Determination of Polyethylene Glycols) in Environmental Samples by the In direct Tensammetric Method, Analyst, 121, 1897, 1996.
  • 7. TOMASZEWSKI K., SZYMANSKI A., LUKASZEWSKI Z., Separation of Polyethylene Glycols) into Fractions by Sequential Liquid-Liquid Extraction, Talanta, 50, 299, 1999.
  • 8. SZYMANSKI A., WYRWAS B., SWIT Z., JAROSZYNSKI T., LUKASZEWSKI Z., Biodegradation of Fatty Alcohol Ethoxylates in the Continuous Flow Activated Sludge Test, Wat. Res., 34, 4101, 2000.
  • 9. SZYMANSKI A., WYRWAS B., SZYMANOWSKA M., LUKASZEWSKI Z., Determination of Short-Chained Polyethylene Glycols) and Ethylene Glycol in Environmental Samples. Wat.Res. 35, 3599, 2001.
  • 10. STEBER J., WIERICH P., The Environmental Fate of Detergent Range Fatty Alcohol Ethoxylates - Biodegradation Studies with 14C-Labelled Model Surfactant. Tenside Deterg., 20, 183, 1983.
  • 11. SWISHER R.D., "Surfactant Biodegradation", Marcel Dekker, Inc., New York and Basel, 1987.
  • 12. KRAVETZ L., CHUNG H., GUIN K.F., SHEBS W.T., SMITH L.S., Primary and ultimate biodegradation of an alcohol ethoxylate and a nonylphenol ethoxylate under average winter conditions in the United States. Tenside Deterg., 21,1, 1984.
  • 13. PATTERSON S.J., SCOTT C.C. .TUCKER K.B.E.,. Nonionic Detergent Degradation. III. Initial Mechanism of the Degradation. J.Am.Oil Chem.Soc., 47, 37, 1970.
  • 14. AHEL M., GIGER W., KOCH M., Behaviour of Alkylphenol Polyethoxylate Surfactants in the Aquatic Environment. I. Occurrence and Transformation in Sewage Treatment, Wat. Res., 28, 1131, 1994.
  • 15. SCHOBERL P., KUNKEL E., ESPETER K., Vergleichende Untersuchungen liber den mikrobiellen Metabolismus eines Nonylphenol- und eines Oxoalcohol-Ethoxylates (Compara tive Studies of Microbal Metabolism of Nonylphenol- and Oxoalcohol Ethoxylates), Tenside Deterg., 18, 64, 1981.
  • 16. WICKBOLD R., Zur Bestimmung nichtionischer Tenside in Fluss- und Abwasser (On the Determination of Non-Ionic Surfactants in River Water and Sewage). Tenside Deterg., 9, 173, 1972.
  • 17. SZYMANSKI A, WYRWAS B., BUBIEN E, KUROSZ T., HRECZUCH W., ZEMBRZUSKI W., LUKASZEWSKI Z., Biodegradation of Oxo-Alcohol Ethoxylates in the Continu ous Flow Activated Sludge Test, Wat.Res.,, in press.
  • 18. OECD Guideline for Testing of Chemicals. OECD 301E Test: Ready Biodegradability: Modified OECD Screening Test, Paris, 1981.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

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