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2008 | 13 | 1 |

Tytuł artykułu

Assessment of heavy metal contamination of soils impacted by a zinc smelter activity

Treść / Zawartość

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
Four metals (Cu, Zn, Pb and Cd) were assayed in soils within the impact zone of the Miasteczko Slaskie Zinc Smelter (southern Poland). The investigated area is afforested and has been subjected for a long time to intensive deposition of metal-bearing dusts. Soil pHKCl varied broadly from very acidic (pHKCl = 3.4) to slightly alkaline (pHKCl = 7.2). Organic carbon (Corg) content fluctuated within a large range, i.e., 5.5 - 66.4 g kg-1, whereas the cation exchange capacity (CEC) was in most cases markedly low (from 1.4 to 5.9 cmol(+)kg-1), with exception for two sites (C and D) exhibiting values of 26.8 and 15.1 cmol(+)kg-1, respectively. Total Zn, Pb and Cd contents exceeded manifold their respective levels in the Earth crust (reference value - RV)) as well as those suggested as background levels for Poland (BLP). The assessment of the contamination of soils by these metals was undertaken on the basis of geoaccumulation indices (lgeo), contamination factors Cl and degrees of contamination (Cdeg). The overall metal contamination represented practically two classes: low contamination for Cu; considerable to extreme contamination (in ascending order) for Zn, Cd, and Pb. The contribution (BLP-based assessment) of each metal to the degree of contamination index varied from 2.14 % (for Cu), via 26.33% (for Zn) to quite equally for Cd and Pb, both representing 35.22% and 36.32, respectively. It is worth pointing out that copper was the sole metal to threaten the least (Figure 1) the soils of the investigated ecosystem.

Wydawca

-

Rocznik

Tom

13

Numer

1

Opis fizyczny

p.5-16,fig.,ref

Twórcy

autor
  • Agricultural University in Poznan, Wojska Polskiego 71F, 60-625 Poznan, Poland
autor

Bibliografia

  • Baize D., Terckeman T. 2001. Of the necessity of knowledge of the natural pedogeochemical background content in the evaluation of the contamination of soils by trace elements. Sci. Total Environ., 264, 127-139.
  • Blaser P., Zimmermann S., Luster J., Shotyk W. 2000. Critical examination of trace element enrichments and depletions in soils. As, Cr, Cu, Ni, Pb, and Zn in Swiss forest soils. Sci. Total Environ., 249, 257-280.
  • Buczkowski R., Kondzielski I., Szymański T. 2002. Methods for the remediation of soils contaminated by heavy metals. Mikolaj Kopernik University Editions, Torun. First Edition, 110 p.
  • Boruvka L.S., Kristoufkova L., Kozak J., Huan Wei C. 1997. Speciation of cadmium, lead and zinc in heavily polluted soils. Rostlina Vyroba, 43: 187-192.
  • Diatta J.B., Grzebisz W., Apolinarska K. 2003. A study of soil pollution by heavy metals in the city of Poznan (Poland) using Dandelion (Taraxacum officinale) as a bioindicator. EJPAU, 6(2): 9 (http:/www.ejpau.media.pl).
  • Fagiewicz K., Kozacki L., Prus-Głowacki W., Chudzińska E., Wojnicka-Półtorak A. 2006. Geneticenvironmental controls of the tolerance of forest Trees to industrial pollution. Archiv. Environ. Protect., 32(1): 73-88.
  • Gee G.W., Bauder J.W. 1986. Particle size analysis. In Methods of Soil Analysis. Part 1. Physical and Mineralogical Methods. Klute A. (ed) 2nd ed. Agron. Monogr. 9, ASA and SSSA, Madison, WI. p. 383-411.
  • Grzebisz W., Kocialkowski W. Z., Chudziński B. 1997. Copper geochemistry and availability in soils contaminated by a copper smelter. J Geochem. Exploration, 58: 301-307.
  • Hakanson L. 1980. An ecological risk index for aquatic pollution control. A sedimentological approach. Wat. Res., 14: 975-1001.
  • International Standard. 1995. Soil Quality - Extraction of trace elements soluble in aqua regia. ISO 11466, Geneva.
  • Kabala C., Singh B.R. 2001. Fractionation and mobility of copper, lead and zinc in soil profiles in the vicinity of a copper smelter. J. Environ. Qual., 30: 485-492.
  • Kabata-Pendias A. 1995. Heavy metals in soils - issues in Central and Eastern Europe. Int. Conf., Hamburg, 1: 20-27.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

bwmeta1.element.agro-article-29ccf145-3dc9-4dd2-ac2c-809bf685efc1
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