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Czasopismo

2000 | 26 |

Tytuł artykułu

Variable surface charge of selected peat materials as determined from back titration

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Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
The surface charge studies were conducted on peat materials at various states of the secondary transformation characterized by W1 index. A back titration method for the determination of the variable surface charge was applied and distribution of the apparent surface dissociation constant for investigated soils were determined. In this method the peat suspensions were titrated with 0.1 N NaOH in IN NaCl solution. For weakly and medium secondary peats positive correlation between quality of the surface charge and the W1 index was found. The best correlation appeared between the surface charge and the summary content of fulvic and humic acids. However, for proper moorsh material two populations can be distinguished. For all samples very strongly acidic surface sites are dominant. Furthermore, the average apparent surface dissociation constant values were similar for all peat-moorsh soils.

Wydawca

-

Czasopismo

Rocznik

Tom

26

Opis fizyczny

p.51-58,fig.

Twórcy

  • Polish Academy of Sciences, Doswiadczalna 4, 20-290 Lublin, Poland

Bibliografia

  • 1. Bambalov N.N., Belen'kaya T.Ya.: Fractional and group composition of organic; matter in virgin and red aimed peat soils (in Russian). Pochvovedenie. 12: 1431-1437, 1998 .
  • 2. De Wit J.CM., Van Rimsdijk W.H., Nederlof M.M., Kinniburgh D.G., Koopal L.K.: Analysis of ion binding on humic substances and the determination of intrinsic affinity distribution. Analítica Chimica Ada. 232: 189-207, 1990.
  • 3. Duquette M., Headers hot W.: Soil surface charge evaluation by back titration. Soil Sci. Soc.Am. J. 57; 1222-1234, 1993.
  • 4. Gawlik J., Harkot W.: Influence of the kind of moorsh and the state of its tran sformation on the germination and growth of Lolium perenne in the pot plant experiment during spring-summer cycle. Acta Agrophysiea,26, 25-40, 2000.
  • 5. Gawlik J,: An attempt to evaluate changes in the water reliability of peat soils in the context of their advancing degradation, Polish J. Soil Sci,, 25: 81-86, 1993,
  • 6. Huang C.P.: In: Adsorption of Inorganics at Solid-Liquid Interfaces. M.A, Anderson and A.J. Rubin, Eds. Ann Arbor Scicnce, Michigan. 183-218, 198!.
  • 7. Józefaciuk G., Shin J.S.: A modified back-titration method to measure soil titration curves minimizing soil acidity and dilution effects. Korean J. Soil Sci. and Fertilizer. 29/4:321-327,1996.
  • 8. Józefaciuk fi., Shin J.S.: Distribution of apparent surface dissociation constants of some Korean soils as determined from back titration curves. Korean J. Soil Sci. and Fertilizer. 29/4: 328-335, 1996.
  • 9. Nederlof M.M., De Wit J.C., Riemsdijk W.H., Koopal L.K.: Determination of proton affinity distributions for humic substances. Environ. Sci. Technol. 27: 846-854, 1993.
  • 10. Sposito G,: The Chemistry of Soils: Soil Organic matter. NY, Oxford, Oxford University Press. 42-65, 1989.
  • 11. Van Riemsdijk W.H., Koopal L.K., De Wit J.C.M.: Heterogeneity and electrolyte adsorption: intrinsic and electrostatic effects. Neth. J. Soil Sci, 35: 241-257, 1987.

Typ dokumentu

Bibliografia

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