Removal of Pb(II) metal ions from aqueous solutions using chitosan-vanillin derivatives of chelating polymers

• Autorzy: Alakhras F. , Al-Shahrani H. , Al-Abbad E. , Al-Rimawi R. , Ouerfelli N.
• Języki publikacji: EN

Abstrakty

EN

Our study investigates the removal of Pb(II) ions found in aqueous solutions using chitosan-vanillin polymeric material. The effects of pH, agitation time, adsorbent mass, and initial amount of studied ion on the chelation process have been carried out using batch experiments. The quantity of residual ions has been estimated via atomic absorption spectrometry. The polymers are characterized using infrared spectroscopy, TGA, SEM, and BET surface area. The highest removal of Pb(II) ions achieved by polymers I and II was at pH 6. The Langmuir isotherm worked as the greatest explanation for the experimental outcome with highest chelation capability equal to 23.3 mg g⁻¹ for polymer I and 66.23 mg g⁻¹ for polymer II. Kinetic studies revealed that chemisorption was the rate-determining step, whereas the uptake was natural and endothermic.

• Wydawca: -
• Czasopismo: Polish Journal of Environmental Studies
• Rocznik: 2019
• Tom: 28
• Numer: 3
• Opis fizyczny: p.1523-1534,fig.,ref.

Twórcy

autor

Alakhras F.

• Department of Chemistry, College of Science, Imam Abdulrahman Bin Faisal University, Dammam, Saudi Arabia

autor

Al-Shahrani H.

• Department of Chemistry, College of Science, Imam Abdulrahman Bin Faisal University, Dammam, Saudi Arabia

autor

Al-Abbad E.

• Department of Chemistry, College of Science, Imam Abdulrahman Bin Faisal University, Dammam, Saudi Arabia

autor

Al-Rimawi R.

• Depertment of Chemistry and Chemical Technology, Faculty of Science and Technology, Al-Quds University, Jerusalem, Palestine

autor

Ouerfelli N.

• Department of Chemistry, College of Science, Imam Abdulrahman Bin Faisal University, Dammam, Saudi Arabia

Bibliografia

• 1. JAISHANKAR M., TSETEN T., ANBALAGAN N., MATHEW B., BEEREGOWDA N. Toxicity, mechanism and health effects of some heavy metals. Interdiscip. Toxicol. 7, 60, 2014.
• 2. BHATTACHARYYA K.G., GUPTA S.S. Adsorption of a few heavy metals on natural and modified kaolinite and montmorillonite: A review. Adv. Colloid Interface Sci. 140, 114, 2008.
• 3. FENGLIAN F., WANG Q. Removal of heavy metal ions from wastewaters: A review. J. Environ. Manag. 92, 407, 2011.
• 4. PILLAI S.S., DEEPA B., ABRAHAM E., GIRIJA N., GEETHA P., JACOB L., KOSHY M. Biosorption of Cd(II) from aqueous solution using xanthated nano banana cellulose: equilibrium and kinetic studies. Ecotoxicol. Environ. Saf. 98, 352, 2013.
• 5. ZHOU F., CHENG Y., GAN L., CHEN Z., MEGHARAJ M., NAIDU R. Hydrogen-rich water confers plant tolerance to mercury toxicity in alfalfa seedlings. Environ. Saf. 105, 1, 2014.
• 6. NGAH W.S., TEONG L.C., HANAFIAH M.A.K.M. Adsorption of dyes and heavy metal ions by chitosan composites: A review. Carbohydr. Polym. 83, 1446, 2011.
• 7. WITEK-KROWIAK A., SZAFRAN R., MODELSKI S. Biosorption of heavy metals from aqueous solutions onto peanut shell as a low-cost biosorbent. Desalination. 265, 126, 2011.
• 8. WANG J., CHEN C. Chitosan-based biosorbents: Modification and application for biosorption of heavy metals and radionuclides. Bioresour. Technol. 160, 129, 2014.
• 9. FENG N., GUO X., LIANG S., ZHU Y., LIU J. Biosorption of heavy metals from aqueous solutions by chemically modified orange peel. J. Hazard. Mater. 185, 49, 2011.
• 10. PRABHU S.M., MEENAKSHI S. Enriched fluoride sorption using chitosan supported mixed metal oxides beads: Synthesis, characterization and mechanism. J. Water Proc. Eng. 2, 96, 2014.
• 11. BHATTARI N., GUNN J., ZHANG M. Chitosan-based hydrogels for controlled, localized drug delivery. Adv. Drug Delivery Rev. 62, 83, 2010.
• 12. JAYAKUMAR R., PRABAHARAN M., NAIR S.V., TAMURA H. Novel chitin and chitosan nanofibers in biomedical applications. Biotechnol. Adv. 28, 142, 2010.
• 13. WU F.C., TSENG R.L., JUANG R.S. A review and experimental verification of using chitosan and its derivatives as adsorbents for selected heavy metals. J. Environ. Manag. 91, 798, 2010.
• 14. JANA S., SAIKIA A., PURKAIT M.K., MOHANTY K. Chitosan based ceramic ultrafiltration membrane: Preparation, characterization and application to remove Hg(II) and As(III) using polymer enhanced ultrafiltration. Chem. Eng. J. 170, 209, 2011.
• 15. VUNAIN E., MISHRA A.K., MAMBA B.B. Dendrimers, mesoporous silicas and chitosan-based nanosorbents for the removal of heavy-metal ions: A review. Inter. J. Biolog. Macromol. 86, 570, 2016.
• 16. EMARA A., TAWAB M., EL-GHAMRY M.A., ELSABEE, M. Metal uptake by chitosan derivatives and structure studies of the polymer metal complexes. Carbohydr. Polym. 83, 192, 2011.
• 17. CHEN A.H., LIU S.C., CHEN C.Y. Comparative adsorption of Cu(II), Zn(II), and Pb(II) ions in aqueous solution on the crosslinked chitosan with epichlorohydrin. J. Hazard Mater. 154, 184, 2008.
• 18. KRISHNAPRIYA K.R., KANDASWAMY M. Synthesis and characterization of a crosslinked chitosan derivative with a complexing agent and its adsorption studies toward metal (II) ions. Carbohydr. Res. 344, 1632, 2009.
• 19. NGAH W.W., FATINATHAN S. Pb (II) biosorption using chitosan and chitosan derivatives beads: Equilibrium, ion exchange and mechanism studies. J. Environ. Sci. 22, 338, 2010.
• 20. KOLODYNSKA D. Chitosan as an effective low-cost sorbent of heavy metal complexes with the polyaspartic acid. Chem. Eng. J. 173, 520, 2011.
• 21. AMARASEKARA A.S., RAZZAQ A. Vanillin-Based Polymers - part II: Synthesis of Schiff Base Polymers of Divanillin and Their Chelation with Metal Ions. ISRN Poly. Sci. 2012.
• 22. EDOKPAYI J.N., ODIYO J.O., POPOOLA E.O., ALAYANDE O.S., MSAGATI T.A. Synthesis and Characterization of Biopolymeric Chitosan Derived from Land Snail Shells and it’s Potential for Pb²⁺ Removal from Aqueous Solution. Materials. 8, 8630, 2015.
• 23. MALEKI A., PAJOOTAN E., HAYATI B.J. Ethyl acrylate grafted chitosan for heavy metal removal from wastewater: Equilibrium, kinetic and thermodynamic studies. Taiwan Institute Chem. Eng. 51, 127, 2015.
• 24. ROCHA L.S., ALMEIDA Â., NUNES C., HENRIQUES B., COIMBRA M.A., LOPES C.B., PEREIRA E. Simple and effective chitosan based films for the removal of Hg from waters: Equilibrium, kinetic and ionic competition. Chem. Eng. J. 300, 217, 2016.
• 25. SHUKLA S.K., MISHRA A.K., AROTIBA O.A., MAMBA B.B. Chitosan-based nanomaterials: A state-of-the-art review. Inter. J. Biolog. Macromol. 59, 46, 2013.
• 26. KAYA İ., BILICI A., GUL M. Schiff base substitute polyphenol and its metal complexes derived from o-vanillin with 2,3-diaminopyridine: synthesis, characterization, thermal, and conductivity properties. Poly. Advanced Tech. 19, 1154, 2008.
• 27. WANG H., SUN W., XIA C. An easily recoverable and efficient catalyst for heterogeneous cyclopropanation of olefins. J. Mol. Catal. A-Chem. 206, 199, 2003.
• 28. IBRAHIM M.B., SANI S. Comparative Isotherms Studies on Adsorptive Removal of Congo Red from Wastewater by Watermelon Rinds and Neem-Tree Leaves. Open J. Physic. Chem. 4, 139, 2014.
• 29. ZALLOUM H.M., Al-QODAH Z., MUBARAK M.S. Copper Adsorption on Chitosan-Derived Schiff Bases. J. Macromol. Sci., Part A. 46, 46, 2008.
• 30. CESTARI A.R., VIEIRA E.F., MATTOS C.R. Thermodynamics of the Cu(II) adsorption on thin vanillin-modified chitosan membranes. J. Chem. Thermodynamics 38, 1092, 2006.
• 31. DIAB M.A., EL-SONBATI A.Z., AL-HALAWANY M.M. Thermal Stability and Degradation of Chitosan Modified by Cinnamic Acid. Open J. Polym. Chem. 2, 14, 2012.
• 32. AL HAMOUZ O.C. Synthesis and Characterization of a Novel Series of Cross-Linked (Phenol, Formaldehyde, Alkyldiamine) Terpolymers for the Removal of Toxic Metal Ions from Wastewater. Arab. J. Sci. Eng. 41, 119, 2016.
• 33. ALTUN T., PEHLIVAN E. Removal of Copper(II) Ions from Aqueous Solutions by Walnut-, Hazelnut- and Almond-Shells. Clean. 35, 601, 2007.
• 34. SHAHMOHAMMADI-KALALAGH S.H., BABAZADEH H., NAZEMI A.H., MANSHOURI M. Isotherm and Kinetic Studies on Adsorption of Pb, Zn and Cu by Kaolinite. Caspian J. Env. Sci. 9, 243, 2011.
• 35. DADA A.O., OLALEKAN A.P., OLATUNYA A.M., DADA O. Langmuir, Freundlich, Temkin and Dubinin-Radushkevich Isotherms Studies of Equilibrium Sorption of Zn²⁺ Unto Phosphoric Acid Modified Rice Husk. IOSR J. Appl. Chem. 3, 38, 2012.
• 36. SUBRAMANI S.E., THINAKARAN, N. Isotherm, kinetic and thermodynamic studies on the adsorption behavior of textile dyes onto chitosan. Proc. Safety Environ. Protect. 106, 1, 2017.
• 37. HO Y.S., HUANG C.T., HUANG H.W. Equilibrium sorption isotherm for metal ions on tree fern. Process Biochem. 37, 1421, 2002.
• 38. BOAMAH P.O., ZHANG Q., HUA M., HUANG Y., LIU Y., WANG W., LIU Y. Lead removal onto cross-linked low molecular weight chitosan pyruvic acid derivatives. Carbohydr. Polym. 110, 518, 2014.
• 39. ZULKALI M.M.D., AHMAD A.L., NORULAKMAL N.H. Oryza sativa L. husk as heavy metal adsorbent: Optimization with lead as model solution. Bioresour. Technol. 97, 21, 2006.
• 40. ZHANG B., YU Y., SHUKLA A., SHUKLA S.S., DORRIS, K.L. The removal of heavy metals from aqueous solutions by sawdust adsorption-removal of lead and comparison of its adsorption with copper. J. Hazard. Mater. B 84, 83, 2001.
• 41. MOUNI L., MERABET D., BOUZAZA A., BELKHIRI L. Adsorption of Pb(II) from aqueous solutions using activated carbon developed from Apricot stone. Desalination. 276, 148, 2011.

Identyfikatory

DOI

10.15244/pjoes/89545