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2018 | 17 |

Tytuł artykułu

Synthesis, characterization, structural and optical properties of titanium-dioxide nanoparticles using Glycosmis cochinchinensis Leaf extract and its photocatalytic evaluation and antimicrobial properties

Treść / Zawartość

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
The present study reports on the development of an Eco-friendly, nontoxic, inexpensive and low cost effective method for green synthesis of titanium dioxide nanoparticles, using Glycosmis cochinchinensis leaf extract. X-Ray diffraction (XRD), Ultraviolet spectral studies (UV-Vis), Fourier transform infrared (FTIR) spectroscopy, Scanning electron microscopy and Energy dispersive spectrometry (SEM–EDS) and Transmission electron microscopy (TEM) were used to characterize the TiO2 nanoparticles, while the application of TiO2 nanoparticles was assessed and antimicrobial activity was evaluated photocatalytically. XRD studies indicated that the titanium dioxide nanoparticles were crystalline in nature and in the anatase phase. According to our derived data, TiO2 nanoparticles exhibited maximum absorbance peak at 430 nm in UV-Vis spectroscopy and the band gap energy was to be found to be 3.02 eV. FTIR spectral studies confirm that flavonoids and proteins are the stabilizing agents of the TiO2 nanoparticles. The SEM and TEM images indicate that the morphology of the product is spherical nanoparticles with an average particle size of 40 ±5 nm with standard deviation. The antibacterial activity of the TiO2 nanoparticles was tested against gram positive bacteria (S. saprophyticus and B. subtilis) and gram negative bacteria (E. coli and P. aeruginosa). Accordingly, maximum zone of inhibition was observed against gram negative bacteria. The antifungal activity of the TiO2 nanoparticles was then tested against Aspergillus niger and Trichoderma reesei. Herein, maximum zone of inhibition was found to be 60 mm against T.reesi. Hence, Glycosmis cochinchinensis leaf extract green synthesized TiO2 nanoparticles can be considered to be an effective antimicrobial agent.

Słowa kluczowe

Wydawca

-

Rocznik

Tom

17

Opis fizyczny

p.1-15,fig.,ref.

Twórcy

autor
  • Department of Chemistry, Poompuhar College (Autonomous), Melaiyur - 609107, India
  • Department of Chemistry, Poompuhar College (Autonomous), Melaiyur - 609107, India

Bibliografia

  • [1] Ahmad Ashfaq and Amna Khatoon, Waste Management of Textiles: A Solution to the Environmental Pollution, International Journal of Current Microbiology and Applied Sciences Volume 3, Number 7 (2014) 780-787.
  • [2] Shikha Behera, Ashutosh Debata and P.L.Nayak, Biomedical Applications Of Silver Nanoparticles, Journal of Asian Scientific Research, 1(1) (2011) 27-56.
  • [3] Singanahally T. Aruna and Alexander S. Mukasyan, Combustion synthesis and nanomaterials, Current Opinion in Solid State and Materials Science 12 (2008) 44–50.
  • [4] Ajay Sharma R.K. Karn and S.K. Pandiyan, Synthesis of TiO2 Nanoparticles by Sol-gel Method and Their Characterization, Journal of Basic and Applied Engineering Volume 1, Number 9, October 2014, 1-5.
  • [5] R. Vijayalakshmi and V. Rajendran, Synthesis and characterization of nano-TiO2 via different methods, Archives of Applied Science Research, 2012, 4 (2): 1183-1190.
  • [6] Chau Thanh Nam, Wein-Duo Yang, and Le Minh Duc, Solvothermal Synthesis of TiO2 Photocatalysts in Ketone Solvents with Low Boiling Points, Journal of Nanomaterials Volume 2013 (2013), 11 pages
  • [7] Xuyang Wang, Jianjun Tian, Chengbin Fei, Lili Lv, Yajie Wang and Guozhong Cao, Rapid construction of TiO2 aggregates using microwave assisted synthesis and its application for dye-sensitized solar cells, RSC Adv. 2015, 5, 8622.
  • [8] Ziquan Liu, Ruming Wang, Fangjun Kan and Fuyi Jiang, Synthesis and Characterization of TiO2 Nanoparticles, Asian Journal of Chemistry Vol. 26, No. 3 (2014) 655-659.
  • [9] W. Li, S. Ismat Shah, C.-P. Huang, O. Jung and C. Ni, Metallorganic chemical vapor deposition and characterization of TiO2 nanoparticles, Materials Science and Engineering B96 (2002) 247-253.
  • [10] Roopan SM, Bharathi A, Prabhakarn A, Rahuman AA, Velayutham K, Rajakumar G, Padmaja RD, Lekshmi M and Madhumitha G., Efficient phytosynthesis and structural characterization of rutile TiO2 nanoparticles using Annona squamosa peel extract. Spectrochim Acta A Mol Biomol Spectrosc. 2012 Dec., 98: 86-90
  • [11] M. Sundrarajan and S. Gowri, Green synthesis of titanium dioxide nanoparticles by nyctanthes arbor-tristis leaves extract, Chalcogenide Letters Vol. 8, no. 8, August 2011, 447-451.
  • [12] R. Sharmila Devi, R. Venckatesh, and Rajeshwari Sivaraj, Synthesis of Titanium Dioxide Nanoparticles by Sol-Gel Technique, International Journal of Innovative Research in Science, Engineering and Technology, Vol. 3, Issue 8, August 2014.
  • [13] Anbalagan Krishnasamy, Mohanraj Sundaresan and Pugalenthi Velan, Rapid phytosynthesis of nano-sized titanium using leaf extract of Azadirachta indica, International Journal of ChemTech Research, Vol. 8, No. 4, 2047-2052, 2015.
  • [14] Sergio Valencia, Juan Miguel Marín, Gloria Restrepo, Study of the Bandgap of Synthesized Titanium Dioxide Nanoparticules Using the Sol-Gel Method and a Hydrothermal Treatment, The Open Materials Science Journal 2009, 4: 9-14.
  • [15] Anbalagan Krishnasamy, Mohanraj Sundaresan and Pugalenthi Velan, Rapid phytosynthesis of nano-sized titanium using leaf extract of Azadirachta indica, International Journal of ChemTech Research, Vol. 8, No.4, pp. 2047-2052, 2015.
  • [16] Javad Karimi Andeani and Sasan Mohsenzadeh, Phytosynthesis of Cadmium Oxide Nanoparticles from Achillea wilhelmsii Flowers. Hindawi Publishing Corporation, Journal of Chemistry Volume 2013, Article ID 147613, 4.
  • [17] Abdul Khadar, Dilip Kumar Behara , Meda Kalyan Kumar, Synthesis and Characterization of Controlled Size TiO2 Nanoparticles via Green Route using Aloe vera Extract, International Journal of Science and Research, Volume 5 Issue 11, November 2016, 1913-1916
  • [18] C Malarkodi, K Chitra, S Rajeshkumar, G Gnanajobitha, K Paulkumar, M Vanaja and G Annadurai, Novel eco-friendly synthesis of titanium oxide nanoparticles by using Planomicrobium sp. and its antimicrobial evaluation, Der Pharmacia Sinica, 2013, 4(3): 59-66.
  • [19] T. Phonkhokkong, T. Thongtem, S. Thongtem , A. Phuruangrat, W. Promnopas, synthesis and characterization of tio2 nanopowders for fabrication of dye sensitized solar cells, Digest Journal of Nanomaterials and Biostructures Vol. 11, no. 1, January - march 2016, p. 81-90.
  • [20] Stotaw Talbachew Hayle and Girma Goro Gonfa, Synthesis and Characterization of Titanium Oxide Nanomaterials Using Sol-Gel Method, American Journal of Nano Research and Applications Volume 2, Issue 1, January 2014, Pages 1-7.
  • [21] E. Figgemeier, W. Kylberg, E. Constable, M. Scarisoreanu, R. Alexandrescu, I. Morjan, I. Soare, R. Birjega, E. Popovici, C. Fleaca, L. Gavrila-Florescu, G. Prodan, Titanium dioxide nanoparticles prepared by laser pyrolysis: Synthesis and photocatalytic properties, Applied Surface Science 254 (2007) 1037-1041.
  • [22] K Adavallan and N Krishnakumar, Mulberry leaf extract mediated synthesis of gold nanoparticles and its anti-bacterial activity against human pathogens, Adv. Nat. Sci.: Nanosci. Nanotechnol. 5 (2014) 025018-9.
  • [23] Razi ahmad,meryamsardar, tio2 nanoparticles as an antibacterial agents against E. Coli, International Journal of Innovative Research in Science, Engineering and Technology, Vol. 2, Issue 8, August 2013, 3569-3574.

Typ dokumentu

Bibliografia

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Identyfikator YADDA

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