Adsorption of zinc and copper heavy metal ions from smelting wastewater using modified lava particles

• Autorzy: Chun-rong W. , Xin R. , Wen-xiu L. , Zhi-Fei H. , Chao K. , Qi G.
• Języki publikacji: EN

Abstrakty

EN

This paper investigated the ability of modified lava particles (MLP), a kind of modified surface media from volcanic eruption, to remove Cu(II) and Zn(II) from simulated smelting wastewater. The equilibrium adsorptive quantity was determined as a function of the initial pH, temperature, MLP dosage, and contact time in a batch test. The results showed that the metal ions uptake by MLP was rapid, and the equilibrium time was 8 h at 25ºC and pH 6, especially within 5-60 min, 80% equilibrium quantity was obtained. With the increase of initial pH value (from 3 to 6), the removal efficiency of Cu(II) and Zn(II) was also increase to 85.31% and 58.21%, respectively, but when pH was more than 6, sedimentation was found. Temperature and thermodynamic studies for the present adsorption process were performed at 15, 20, 25, 30, and 35ºC by determining the values of ΔGº and ΔHº, and it was confirmed that the adsorption process is endothermic and spontaneous. And the optimal MLP dosage of 10 g/L and 6 g/L were obtained for Cu(II) and Zn(II) removal, respectively. The mechanism of these two metal ions sorped by MLP was inferred that the hydroxide micro-precipitation and surface hydroxyl complex were predominant.

• Wydawca: -
• Czasopismo: Polish Journal of Environmental Studies
• Rocznik: 2013
• Tom: 22
• Numer: 6
• Opis fizyczny: p.1863-1869,fig.,ref.

Twórcy

autor

Chun-rong W.

• School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083, China

autor

Xin R.

• School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083, China

autor

Wen-xiu L.

• School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083, China

autor

Zhi-Fei H.

• School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083, China

autor

Chao K.

• School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083, China

autor

Qi G.

• School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083, China

Bibliografia

• 1. GUPTA V. K., RASTOGI A. Biosorption of hexavalent chromium by raw and acid-treated green alga Oedogonium hatei from aqueous solutions. J. Hazard. Mater., 163, 396, 2009.
• 2. LIANG N., YANG L.-Y., DAI J.-R., PANG X.-G. Heavy metal pollution in surface water of Linglong gold mining area. China Procedia Environmental Sciences, 10, (Part A), 914, 2011.
• 3. SHAO L.-N., YANG X.-S. Current situation and development of wastewater treatment in China’s non-ferrous metal smelting industry. Nonferrous Metal Engineering, (3), 39, 2011.
• 4. LI P., FAN J-H., LIU R., YU B., CHENG J.-D., YU S.-L., CHEN L.-J., SHAN X.-L. A study on pollution characteristics and removal performance of heavy metals in a tannery and textile dyeing industrial park wastewater treatment plant. Environmental Engineering, 30, 101, 2012.
• 5. SHEN X.-Q., SHEN A.-L. Dissolved characteristics of heavy metal in waste battery and toxic effect on marine organisms. Asian Journal of Ecotoxicology, 5, (1), 63, 2010.
• 6. IYER A., MODY K., JHA B. Biosorption of heavy metals by a marine bacterium. Mar. Pollut. Bull., 50, 340, 2005.
• 7. HUANG J.-T., XIONG F., XIE W.-L., ZHONG L. Process in researches on treatment of heavy metal wastewater by adsorption process. Technology of Water Treatment, 32, (2), 9, 2006.
• 8. GUPTA V. K., ALI I., SALEH T A., NAYAKA A., AGARWALC S. Chemical treatment technologies for waste-water recycling – an overview. RSC Advances, 2, 6380, 2012.
• 9. SALEH T. A., GUPTA V. K. Column with CNT/magnesium oxide composite for lead(II) removal from water. Environmental Science and Pollution Research, 19, 1224, 2012.
• 10. REDDY D. H. K., LEE S. M., SESHAIAH K. Biosorption of toxic heavy metal ions from water environment using honeycomb biomass – an industrial waste material. Water Air Soil Poll., 223, (9), 5967, 2012.
• 11. GUPTA V. K., RASTOGI A., NAYAK A. Biosorption of nickel onto treated alga (Oedogonium hatei): Application of isotherm and kinetic models. J. Colloid Interf. Sci., 342, 533, 2010.
• 12. GUPTA V. K., RASTOGI A. Biosorption of hexavalent chromium by raw and acid-treated green alga Oedogonium hatei from aqueous solutions. J. Hazard. Mater., 163, 396, 2009.
• 13. ZHAO Q.-L., XIA X.-Q., WANG G.-Z., ZHANG T.-M., YANG E.-T. Lead-Laden wastewater treatment with zeolite and a modified material ANJ. SiC. Research of Environmental Sciences, 24, (9), 1023, 2011.
• 14. GUPTA V. K., SHARMA S. Removal of Zinc from Aqueous Solutions Using Bagasse Fly Ash − a Low Cost Adsorbent. Industrial and Engineering Chemistry Research, 42, (25), 6619, 2003.
• 15. JAINA A. K., GUPTA V. K., BHATNAGARA A., SUHAS. A Comparative Study of Adsorbents Prepared from Industrial Wastes for Removal of Dyes. Separ. Sci. Technol. 38, (2), 463, 2003.
• 16. JAIN A K., GUPTA V. K., JAIN S. Removal of Chlorophenols Using Industrial Wastes, Environ. Sci. Technol., 38, (4), 1195, 2004.
• 17. GUPTA V. K., MITTAL A., MALVIYA A., MITTAL J. Adsorption of carmoisine A from wastewater using waste materials – Bottom ash and deoiled soya. J. Colloid Interf. Sci., 335, 24, 2009.
• 18. GUPTA V. K., ALI I., SAINI V K. Defluoridation of wastewaters using waste carbon slurry. Water Res., 41, 3307, 2007.
• 19. GUPTA V. K., MITTAL A., KRISHNAN L., MITTAL J. Adsorption treatment and recovery of the hazardous dye, Brilliant Blue FCF, over bottom ash and de-oiled soya. J. Colloid Interf. Sci., 293, 16, 2006.
• 20. MITTALA A., KURUP K.L., GUPTA V K. Use of waste materials-Bottom Ash and De-Oiled Soya, as potential adsorbents for the removal of Amaranth from aqueous solutions. J. Hazard. Mater., B117, 171, 2005.
• 21. GUPTA V. K., GUPTA B., RASTOGI A., AGARWALD S., NAYAK A. A comparative investigation on adsorption performances of mesoporous activated carbon prepared from waste rubber tire and activated carbon for a hazardous azo dye-Acid Blue 113. J. Hazard. Mater., 186, 891, 2011.
• 22. MITTAL A, MITTAL J, MALVIYA A, KAUR D, GUPTA V K. Adsorption of hazardous dye crystal violet from wastewater by waste materials. J. Colloid Interf. Sci., 343, 463, 2010.
• 23. MITTAL A., GUPTA V K., MALVIYA A., MITTAL J. Process development for the batch and bulk removal and recovery of a hazardous, water-soluble azo dye (Metanil Yellow) by adsorption over waste materials (Bottom Ash and De-Oiled Soya). J. Hazard. Mater., 151, 821, 2008.
• 24. GUPTA V. K., MITTAL A., KURUP L., MITTAL J. Adsorption of a hazardous dye, erythrosine, over hen feathers. J. Colloid Interf. Sci., 304, 52, 2006.
• 25. GUPTA V K, JAIN R, VARSHNEY S. Removal of Reactofix golden yellow 3 RFN from aqueous solution using wheat husk – An agricultural waste. J. Hazard. Mater., 142, 443, 2007.
• 26. HU J.-L., WAHG C.-R., HE X.-W., SHAO L.-N., LI D., YIN K., WU M. Study on influencing factors of modified lava media for iron and manganese removal from mine water. Chinese Journal of Environmental Engineering, 3, (7), 1199, 2009.
• 27. State Environmental Protection Administration of China. Water and Wastewater Monitoring Analysis Method. Beijing: Chinese Environmental Science, 2002.
• 28. ZHANG X. L., HONG H., LI Z., GUAN J., SCHULZ L. Removal of azobenzene from water by kaolinite. J. Hazard. Mater., 170, 1046, 2009.
• 29. DIVINCENZO J. P., SPARKS D L. Slow sorption kinetics of pentachlorophenol on soil: Concentration effects. Environ. Sci. Technol., 3, 977, 1997.
• 30. WANG J.-G., LV J.-L., CAO Y.-F. Adsorption of cadmium and lead in two typical soils as affected by temperature. J. Soil Water Conserv., 25, (6), 254, 2011.
• 31. JAMES R. O., HESLY T. W. Adsorption of hydrolyzable metal ions at the oxide-water interface. III. A thermodynamic model of adsorption. J. Colloid Interf. Sci., 40, (1), 65, 1972.
• 32. DAI S.-G. Environmental Chemistry (2nd edition). Beijing:Higher Education Press, 175, 2006.
• 33. LIU R.-P., YANG Y.-L., XIA S.-J., HE W.-J., HAN H.-D., LI G.-B. Surface chemistry of hydrous manganese dioxide characterization and its effectiveness of removing pollutants. Environmental Chemistry, 24, (3), 338, 2005.
• 34. BRULE D. G., BROWN J. R., BANCROFT G. M., FYFE W. S. Cation adsorption by hydrous manganese dioxide: A semi-quantitative X-ray photoelectron spectroscopic (ESCA) study. Chem. Geol., 28, 331, 1980.