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2019 | 28 | 4 |
Tytuł artykułu

Kinetic, isotherm and thermodynamic studies on the adsorption behavior of atrazine onto sheep manure-derived biochar

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Experimental and theoretical studies have been conducted to investigate the adsorption of atrazine in aqueous solutions by sheep manure-derived biochar synthesized at 650°C (SMB650). The results of characterization analysis showed that SMB650 possessed large specific surface area and was rich in pore structure and functional groups. The removal efficiency of atrazine by SMB650 was 95.3% under the optimum conditions, of which contact time, initial atrzaine concentration, initial solution pH, SMB650 dosage and temperature were 150 min, 1500 μg/L, 3.0, 1.6 g/L and 25ºC, respectively. The results of kinetic and isotherm studies revealed that the pseudo second-order and the Freundlich model fit the experimental data best (R2>0.98). The adsorption of atrazine onto SMB650 belonged to multi-molecular layer adsorption. The calculated thermodynamic parameters like free energy change (ΔGθ), enthalpy change (ΔHθ) and entropy change (ΔSθ) were -7.8730 to -6.2976 kJ/mol, 17.2179 kJ/mol and 0.0788 kJ/(mol·K), respectively, indicating that the adsorption process of atrazine onto SMB650 was spontaneous, endothermic and entropy-increased. The present study showed that the sheep manure-derived biochar could be used as a promising adsorbent for the removal of atrazine from aqueous solutions.
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  • Faculty of Geosciences and Environmental Engineering, Southwest Jiaotong University, Chengdu, China
  • Department of Architectural and Environmental Engineering, Chengdu Technological University, Chengdu, China
  • Faculty of Geosciences and Environmental Engineering, Southwest Jiaotong University, Chengdu, China
  • Department of Architectural and Environmental Engineering, Chengdu Technological University, Chengdu, China
  • Faculty of Geosciences and Environmental Engineering, Southwest Jiaotong University, Chengdu, China
  • Faculty of Geosciences and Environmental Engineering, Southwest Jiaotong University, Chengdu, China
  • 1. THORPE N., SHIRMOHAMMADI A. Herbicides and nitrates in groundwater of Maryland and childhood cancers: A geographic information systems approach. J. Environ. Sci. Heal C. 23, 261, 2005.
  • 2. BARCO-BONILLA N., ROMERO-GONZALEZ R., PLAZA-BOLANOS P., VIDAL J.L.M., FRENICH A.G. Systematic study of the contamination of wastewater treatment plant effluents by organic priority compounds in Almeria province (SE Spain). Sci. Total Environ. 447, 381, 2013.
  • 3. MORENO-GONZALEZ R., CAMPILLO J.A., GARCIA V., LEON V.M. Seasonal input of regulated and emerging organic pollutants through surface watercourses to a Mediterranean coastal lagoon. Chemosphere. 92 (3), 247, 2013.
  • 4. SINGH S., KUMAR V., CHAUHAN A., DATTA S., WANI A.B., SINGH N., SINGH J. Toxicity, degradation and analysis of the herbicide atrazine. Environ. Chem. Lett. 2, 1, 2017.
  • 5. LASSERRE J.P., FACK F., SERCHI T., REVETS D., PLANCHON S., RENAUT J., HOFFMANN L., GUTLEB A.C., MULLER C.P., BOHN T. Atrazine and pcb 153 and their effects on the proteome of subcellular fractions of human MCF-7 cells. Bba-Proteins Proteom. 1824, 833, 2012.
  • 6. ZHAO X.C., OUYANG W., HAO F.H., LIN C.Y., WANG F.L., HAN S., GENG X.J. Properties comparison of biochars from corn straw with different pretreatment and sorption behaviour of atrazine. Bioresource Technol. 147, 338, 2013.
  • 7. PAL J., DEB M.K., SIRCAR J.K., AGNIHOTRI P.K. Microwave green synthesis of biopolymer-stabilized silver nanoparticles and their adsorption behavior for atrazine. Appl. Water Sci. 5, 181, 2015.
  • 8. WANG P.F., YIN Y.Y., GUO Y., WANG C. Preponderant adsorption for chlorpyrifos over atrazine by wheat strawderived biochar: experimental and theoretical studies. Rsc Adv. 6, 10615, 2016.
  • 9. ALAHABADI A., MOUSSAVI G. Preparation, characterization and atrazine adsorption potential of mesoporous carbonate-induced activated biochar (CAB) from Calligonum Comosum biomass: Parametric experiments and kinetics, equilibrium and thermodynamic modeling. J. Mol. Liq. 242, 40, 2017.
  • 10. MOREIRA A.J., BORGES A.C., GOUVEA L.F.C., MACLEOD T.C.O., FRESCHI G.P.G. The process of atrazine degradation, its mechanism, and the formation of metabolites using UV and UV/MW. J. Photoch. Photobio. A. 347, 160, 2017.
  • 11. YANG J.X., LI J., DONG W.Y., MA J., CAO J., LI T.T., LI J.Y., GU J., LIU P.X. Study on enhanced degradation of atrazine by ozonation in the presence of hydroxylamine. J. Hazard. Mater. 316, 110, 2016.
  • 12. CHENG M., ZENG G.M., HUANG D.L., LAI C., XU P., ZHANG C., LIU Y., WAN J., GONG X.M., ZHU Y.Degradation of atrazine by a novel Fenton-like process and assessment the influence on the treated soil. J. Hazard. Mater. 312, 184, 2016.
  • 13. QIU Y.P., ZHENG Z.Z., ZHOU Z.L., SHENG G.D. Effectiveness and mechanisms of dye adsorption on a straw-based biochar. Bioresource Technol. 100, 5348, 2009.
  • 14. YANG G.X., JIANG H. Amino modification of biochar for enhanced adsorption of copper ions from synthetic wastewater. Water Res. 48, 396, 2014.
  • 15. WANG Z.H., SHEN D.K., SHEN F., LI T.Y. Phosphate adsorption on lanthanum loaded biochar. Chemosphere. 150, 1, 2016.
  • 16. TAN G.C., SUN W.L., XU Y.R., WANG H.Y., XU N. Sorption of mercury (II) and atrazine by biochar, modified biochars and biochar based activated carbon in aqueous solution. Bioresource Technol. 211, 727, 2016.
  • 17. ZHANG W.H., ZHENG J., ZHENG P.P., Qiu R.L. Atrazine immobilization on sludge derived biochar and the interactive influence of coexisting Pb(II) or Cr(VI) ions. Chemosphere. 134, 438, 2015.
  • 18. ZHAO L., DONG Y.H., WANG H. Residues of veterinary antibiotics in manures from feedlot livestock in eight provinces of China. Sci. Total Environ. 408, 1069, 2010.
  • 19. CANG L., WANG Y.J., ZHOU D.M., DONG Y.H. Heavy metals pollution in poultry and livestock feeds and manures under intensive farming in Jiangsu Province, China. J. Environ. Sci.-China. 16, 371, 2004.
  • 20. XIONG X.O., LI Y.X., LI W., LIN C.Y., HAN W., YANG M. Copper content in animal manures and potential risk of soil copper pollution with animal manure use in agriculture. Resour. Conserv. Recy. 54, 985, 2010.
  • 21. MANDAL A., SINGH N., PURAKAYASTHA T.J. Characterization of pesticide sorption behaviour of slow pyrolysis biochars as low cost adsorbent for atrazine and imidacloprid removal. Sci. Total Environ. 577, 376, 2017.
  • 22. FENG D., YU H.M., DENG H., LI F.Z., GE C.J. Adsorption characteristics of norfloxacin by biochar prepared by cassava dreg: kinetics, isotherms, and thermodynamic analysis. Bioresources. 10, 6751, 2015.
  • 23. QIAN J., SHEN M.M., WANG P.F., WANG C., LI K., LIU J.J., LU B.H., TIAN X. Perfluorooctane sulfonate adsorption on powder activated carbon: Effect of phosphate (P) competition, pH, and temperature. Chemosphere. 182, 215, 2017.
  • 24. WANG, L., CHEN, G.C., LING, C., ZHANG, J.F., SZERLAG, K. Adsorption of Ciprofloxacin on to Bamboo Charcoal: Effects of pH, Salinity, Cations, and Phosphate. Environ. Prog. Sustain. 36, 1108, 2017.
  • 25. WEI Z.G., LIANG K., WU Y., ZOU Y.D., ZUO J.H., ARRIAGADA D.C., PAN Z.C., HU G.H. The effect of pH on the adsorption of arsenic(III) and arsenic(V) at the TiO2 anatase [101] surface. J. Colloid Interf. Sci. 462, 252, 2016.
  • 26. KARA S., AYDINER C., DEMIRBAS E., KOBYA M., DIZGE N. Modeling the effects of adsorbent dose and particle size on the adsorption of reactive textile dyes by fly ash. Desalination. 212, 282, 2007.
  • 27. YANG S.T., LI J.X., SHAO D.D., HU J., WANG X.K. Adsorption of Ni(II) on oxidized multi-walled carbon nanotubes: Effect of contact time, pH, foreign ions and PAA. J. Hazard. Mater. 166, 109, 2009.
  • 28. HO Y.S. Review of second-order models for adsorption systems. J. Hazard. Mater. 136, 681, 2006.
  • 29. EL BOURAIE M., MASOUD A.A. Adsorption of phosphate ions from aqueous solution by modified bentonite with magnesium hydroxide Mg(OH)2. Appl. Clay. Sci. 140, 157, 2017.
  • 30. ALJEBOREE A.M., ALKAIM A.F., AL-DUJAILI A.H. Adsorption isotherm, kinetic modeling and thermodynamics of crystal violet dye on coconut huskbased activated carbon. Desalin. Water Treat. 53, 3656, 2015.
  • 31. ALEMAYEHU E., THIELE-BRUHN S., LENNARTZ B. Adsorption behaviour of Cr(VI) onto macro and microvesicular volcanic rocks from water. Sep. Purif. Technol. 78, 55, 2011.
  • 32. KYZAS G.Z., DELIYANNI E.A., MATIS K.A. Activated carbons produced by pyrolysis of waste potato peels: Cobalt ions removal by adsorption. Colloid Surface A. 490, 74, 2016.
  • 33. NAMASIVAYAM C., KAVITHA D. Removal of Congo Red from water by adsorption onto activated carbon prepared from coir pith, an agricultural solid waste. Dyes Pigments. 54 (1), 47, 2002.
  • 34. ABIGAIL M.E.A., CHIDAMBARAM R. Rice husk as a low cost nanosorbent for 2,4-dichlorophenoxyacetic acid removal from aqueous solutions. Ecol. Eng. 92, 97, 2016.
  • 35. MOUSSAVI G., HOSSEINI H., ALAHABADI A. The investigation of diazinon pesticide removal from contaminated water by adsorption onto NH4Cl-induced activated carbon. Chem. Eng. J. 214, 172, 2013.
  • 36. ALI I., ALOTHMAN Z.A., AL-WARTHAN A. Sorption, kinetics and thermodynamics studies of atrazine herbicide removal from water using iron nano-composite material. Int. J. Environ. Sci. Te. 13, 733, 2016.
  • 37. GUPTA V.K., PATHANIA D., SHARMA S., SINGH P. Preparation of bio-based porous carbon by microwave assisted phosphoric acid activation and its use for adsorption of Cr(VI). J. Colloid Interf. Sci. 401, 125, 2017.
  • 38. LI Y.H., DI Z.C., DING J., WU D.H., LUAN Z.K., ZHU Y.Q. Adsorption thermodynamic, kinetic and desorption studies of Pb2+ on carbon nanotubes. Water Res. 39, 605, 2005.
  • 39. CHOWDHURY S., MISHRA R., SAHA P., KUSHWAHA P. Adsorption thermodynamics, kinetics and isosteric heat of adsorption of malachite green onto chemically modified rice husk. Desalination. 265, 159, 2011.
  • 40. JOHIR M.A.H., PRADHAN M., LOGANATHAN P., KANDASAMY J., VIGNESWARAN S. Phosphate adsorption from wastewater using zirconium (IV) hydroxide: Kinetics, thermodynamics and membrane filtration adsorption hybrid system studies. J. Environ. Manage. 167, 167, 2016.
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