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2012 | 21 | 4 |

Tytuł artykułu

Comparing methods of 17alpha-ethinylestradiol (EE2) determination in surface water

Autorzy

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
We compared methods of determination of 17α-ethinyloestradiol (EE2) in surface water in Kielce, Poland. EE2 plays a role as a contraception agent and it is commonly used as an active agent in contraception pills. During studies three methods of EE2 determination were checked: TLC, HPLC, and ELISA assay. Samples of contaminated water were taken from eight points on four rivers crossing Kielce city, tap water, and sludge in a sewage treatment plant (STP). Assays revealed that EE2 is present in river water in amounts of 3.2 ng/Lto 6.29 ng/L. The EE2 removal process in STP is ineffective, removings only 1.3%. EE2 was not detected in Kielce's tap water. No correlation between fecal microbial contamination and EDS presence was determined.

Wydawca

-

Rocznik

Tom

21

Numer

4

Opis fizyczny

p.1089-1093,fig.,ref.

Twórcy

autor
  • Department of Microbiology, Institute of Biology, Jan Kochanowski University in Kielce, Swietokrzyska 15, 25-406, Kielce, Poland
autor

Bibliografia

  • 1. ZORITA S., HALLGREN P., MATHIASSON L. Steroid hormone determination in water using an environmentally friendly membrane based extraction technique. J Chromatogr A 1192, 1, 2008.
  • 2. ZUO Y., ZHANG K., DENG Y. Occurrence and photochemical degradation of 17 alpha-ethinylestradiol in Acushnet River Estuary, Chemosphere, 63, 1583, 2006.
  • 3. HOHENBLUM P., GANS O., MOCHE W, SCHARF S., LORBEER G. Monitoring of selected estrogenie hormones and industrial chemicals in groundwaters and surface waters in Austria. Sci Tot Environ 333, 185, 2004.
  • 4. AURIOL M., FILALI-MEKNASSI Y., TYAGI R.D., ADAMS C. D., SURAMPALLI R.Y. Endocrine disrupting compounds removal from wastewater, a new challenge. Proc Biochem 41, 525, 2006.
  • 5. BODZEK M., DUDZIAK M. Removal of Natural Estrogens and Synthetic Compounds Considered to be Endocrine Disrupting Substances (EDs) by Coagulation and Nanofiltration. Pol. J. Environ. Stud. 15, (1), 35, 2006.
  • 6. MULLER M., RABENOELINA F., BALAGUER P., PATUREAU D., LEMENACH K., BUDZINSKI H., BARCELO D., LOPEZ DE ALDA M., KUSTER M., DELGENES J.P., HERNANDEZ-RAQUET G. Chemical and biological analysis of endocrine-disrupting hormones and estrogenic activity in an advanced sewage treatment plant. Environ. Toxicol Chem, 27, (8), 1649, 2008.
  • 7. LOPEZ DE ALDA M.J., BARCELO D. Determination of steroid sex hormones and related synthetic compounds considered as endocrine disrupters in water by fullyautomated on-line solid-phase extraction-liquid chromatography-diode array detection. J Chromatogr A 911, 203, 2001.
  • 8. KIDD C.E., KIDD MR., HOFMANN H.A. Measuring multiple hormones from a single water sample using enzyme immunoassays. Gen Comp Endocrinol. 165, 277, 2010.
  • 9. SALIERNO J.D., KANE A.S. 17a-ethinylestradiol alters reproductive behaviors, circulating hormones, and sexual morphology in male fathead minnows (Pimephales prometas) Environ. Toxicol Chem, 28, (5), 953, 2009.
  • 10. VARELA R.M., DAO T.L. Estrogen Synthesis and Estradiol Binding by Human Mammary Tumors. Cancer Res 38, 2429,1978.
  • 11. LISKOWSKI L., WOLF R.C., CHANDLER S., MEYER R.K. Urinary estrogen excretion in pregnant rhesus monkeys. Biol Reprod 3, 55,1970.
  • 12. PN-EN ISO 6222. Water quality - Enumeration of cultur- able micro-organisms - Colony count by inoculation in a nutrient agar culture medium. 2004
  • 13. PN-EN ISO 9308-1. Water quality - Detection and enumeration of Escherichia coli and coliform bacteria - Part 1: Membrane filtration method. 2004.
  • 14. ZHANG K., ZUO Y. Pitfalls and solution for simultaneous determination of estrone and 17α-ethinylestradiol by gas chromatography - mass spectrometry after derivatization with N,O-bis(trimethylsilyl)trifluoroacetamide. Anal. Chim. Acta 554, 190, 2005.
  • 15. ZUO Y., ZHANG K., LIN Y. Microwave-accelerated derivatization for the simultaneous gas chromatography-mass spectrometric analysis of natural and synthetic estrogenic steroid hormones. J. Chromatography A 1148, 211, 2007.
  • 16. ZUO Y., LIN Y. Solvent effects on the silylation-gas chromatography-mass spectrometric determination of natural and synthetic estrogenic steroid hormones: Comment on "Formation of chlorinated estrones via hypochlorous disinfection of wastewater effluent containing estrone," Chemosphere, 69, 1175, 2007.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

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