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2014 | 23 | 5 |

Tytuł artykułu

Research of the efficiency of a secondary catalyst for nitrous oxide emission reduction at a nitric acid plant

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
Installing a secondary decomposing catalyst is an effective method for nitrous oxide emission reduction at a nitric acid production facility. Before the installation of a decomposing catalyst at a nitric acid plant in Devnya, Bulgaria, the N2O concentration in the tail gas was 1,754 mg/Nm3 while after the installation the N2O concentration was 212 mg/Nm3, which is almost 8.3 times lower. For the entire monitoring period a total N2O emission reduction of 7,021 Mg was achieved. Research of the catalyst’s behavior during the production campaign has been done, proving that the achieved reduction level depends on the catalyst’s functional activity and the technological process conditions. Planning the duration of the decomposing catalyst’s efficient operation throughout N2O monitoring data analysis provides effective emission reduction.

Słowa kluczowe

Wydawca

-

Rocznik

Tom

23

Numer

5

Opis fizyczny

p.1875-1880,fig.,ref.

Twórcy

autor
  • Department of Ecology and Environmental Protection, Technical University Varna, Studentska 1, 9010 Varna, Bulgaria
  • Department of Ecology and Environmental Protection, Technical University Varna, Studentska 1, 9010 Varna, Bulgaria

Bibliografia

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  • 5. IPCC Third Assessment Report, Climate Change 2001: The Scientific Basis. Cambridge University Press: Cambridge, pp. 239-287, 2001.
  • 6. Directive 2009/29/EC of the European Parliament and of the Council of 23 April 2009 amending Directive 2003/87/EC so as to improve and extend the greenhouse gas emission allowance trading scheme of the Community, OB L 140, 63, 2009.
  • 7. European Comission, Integrated Pollution Prevention and Control. Reference Document on BAT for the manufacture of Large Volume Inorganic Chemicals - Ammonia, Acids and Fertilizers, 2007.
  • 8. Agency for Energy and the Environment. Reduction of Nitrous Oxide in the Nitric Acid Industry. The Hague, 2001.
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  • 11. HAIBO Z., HUANG Z., SUN C., QIN F., XIONG D., SHEN W., XU H. Catalytic Decomposition of N2O over CuxCe1 xOy Mixed Oxides. Appl. Catal. B-Environ., 125, 492, 2012.
  • 12. AMROUSSE R., TSUTSUMI A., BACHAR A., LAHCENE D. N2O Catalytic Decomposition over Nano- sized Particles of Co-substituted Fe3O4 Substrates. Appl. Catal. A- Gen., 450, 253, 2013.
  • 13. AMROUSSE R., KATSUMI T. Substituted Ferrite MxFe1- xFe2O4 (M = Mn, Zn) Catalysts for N2O Catalytic Decomposition Processes. Catal. Commun., 26, 194, 2012.
  • 14. IWANEK E., KRAWCZYK K., PETRYK J., SOBCZAK J. W., KASZKUR Z. Direct Nitrous Oxide Decomposition with a CoOx-CeO2 Catalyst. Appl. Catal. B-Environ., 106, (3-4), 416, 2011.
  • 15. DACQUIN J. P., LANCELOT C., DUJARDIN C., DA COSTA P., DJEGA-MARIADASSOU G., BEAUNIER P., KALIAGUINE S., VAUDREUIL S., ROYER S., GRANGER P. Influence of Preparation Methods of LaCoO3 on the Catalytic Performances in the Decomposition of N2O. Appl. Catal. B-Environ., 91, (3-4), 596, 2009.
  • 16. KOMVOKIS V. G., MARTI M., DELIMITIS A., VASA- LOS I. A., TRIANTAFYLLIDIS K. S. Catalytic Decomposition of N2O over Highly Active Supported Ru Nanoparticles (<3 nm) Prepared by Chemical Reduction with Ethylene Glycol. Appl. Catal. B-Environ., 103, (1-2), 62, 2011.
  • 17. RICO-PEREZ V., PARRES-ESCLAPEZ S., ILLAN- GOMEZ M. J., SALINAS-MARTINEZ DE LECEA C., BUENO-LOPEZ A. Preparation, Characterisation and N2O Decomposition Activity of Honeycomb Monolith-supported Rh/Ce09Pr01O2 Catalysts. Appl. Catal. B-Environ., 107, (1-2), 18, 2011.
  • 18. HAIBO Z., HU P., HUANG Z., QIN F., SHEN W., XU H. Preparation of NiCe Mixed Oxides for Catalytic Decomposition of N2O. Ind. Eng. Chem. Res., 52, (12), 4504, 2013.
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  • 20. AMROUSSE R., CHANG P., CHOKLATI A., FRICHE A., RAI M., BACHAR A., FOLLET-HOUTTEMANE C., HORI K. Catalytic Decomposition of N2O over Ni and Mg- Magnetite Catalysts. Catal. Sci. Technol., 3, 2288, 2013.
  • 21. LENOIR G., KOPPERBUD T., NIRISEN O. Yara De-N2O Secondary Abatement from Nitric Acid Production - a Proven Technology. Nitrogen2006, Vienna Austria, 12-15 March 2006, pp. 113-119, 2006.
  • 22. Nanjing Chemical Industries Co Ltd (NCIC) Nitrous Oxide Abatement Project. 2004.
  • 23. JANTSCH U. Industrial Application of Secondary N2O Abatement Technology in the Ostwald Process. Nitrogen2006, Vienna Austria 12-15 March, pp. 2, 2006.
  • 24. KUHN G. Experiments on N2O Destruction in Ammonia Burners. In: ADEME/InfoMil, NOXCONF 2001: Collection of papers "International conference industrial atmospheric pollution, 21st and 22nd March 2001, Paris (France), ADEME (France)/InfoMil (The Netherlands), 2001.
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Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

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