MCPA decomposition method in soil matrix using ozone as an oxidant

• Autorzy: Balawejder M. , Antos P. , Jozefczyk R. , Pieniazek M. , Odzimek E.

Warianty tytułu

PL

Metoda rozkładu MCPA w matrycy glebowej z użyciem ozonu jako utleniacza

• Języki publikacji: EN

Abstrakty

EN

In presented research a method for remediation of MCPA contaminated soil based on the combination of fluidization process technique and ozone was utilized. Exposition of soil contaminated with MCPA at the concentration of 0,1 % w/w on the a mixture of air and ozone allowed for removal of over 90% of MCPA in form of MCPA 2-ethylhexanol-ester (MCPA 2-EHE) in laboratory conditions. The efficacy of the method was proven by GC-MS analysis of MCPA concentration profile during soil remediation procedure and by comparing of kinetic data, such as half life time, with the natural half life time of MCPA in the soil.

Słowa kluczowe

EN

2-methyl-4-chlorophenoxyacetic acid; decomposition method; soil matrix; ozone; oxidant; soil contamination

• Wydawca: -
• Czasopismo: Polish Journal of Soil Science
• Rocznik: 2014
• Tom: 47
• Numer: 2
• Opis fizyczny: p.64-70,fig.,ref.

Twórcy

autor

Balawejder M.

• Chair of Chemistry and Food Toxicology, Faculty of Biology and Agriculture, University of Rzeszow, Cwiklinskiej 1, 35-601 Rzeszow, Poland

autor

Antos P.

• Chair of Chemistry and Food Toxicology, Faculty of Biology and Agriculture, University of Rzeszow, Cwiklinskiej 1, 35-601 Rzeszow, Poland

autor

Jozefczyk R.

• Chair of Chemistry and Food Toxicology, Faculty of Biology and Agriculture, University of Rzeszow, Cwiklinskiej 1, 35-601 Rzeszow, Poland

autor

Pieniazek M.

• Department of Soil Science Environmental Chemistry and Hydrology, Faculty of Biology and Agriculture, University of Rzeszow, Cwiklinskiej 1, 35-601 Rzeszow, Poland

autor

Odzimek E.

• Chair of Chemistry and Food Toxicology, Faculty of Biology and Agriculture, University of Rzeszow, Cwiklinskiej 1, 35-601 Rzeszow, Poland

Bibliografia

• [1] A b r a m o v i c B.F., S o j i c D.V., A n d e r l u h V.B., A b a z o v i c N.D., C o m o r M.I.: Desalination, 244(1–3), 293, 2009.
• [2] A n t o s P., K u r d z i e l A., S a d ł o S., B a l a w e j d e r M.: J. Plant Prot. Res., 53(1), 48, 2013.
• [3] B a l a w e j d e r M., A n t o s P., C z y j t-K u r y ł o S., J ó z e f c z y k R., P i e n i ą ż e k M.: Ozone Sci. Eng., 36, 166, 2014.
• [4] B a l a w e j d e r M., A n t o s P., J ó z e f c z y k R., P i ą t k o w s k i W.: Patent application P.403458, 2013.
• [5] B a l a w e j d e r M., A n t o s P., S a d ł o S.: Rocz. Państ. Zakł. Hig., 64(1), 13, 2013.
• [6] B a l a w e j d e r M.: Patent application P.401853, 2012.
• [7] G i m e n o O., A g u i n a c o A., R e y A., B e l t r á n N o v i l l o F.J., R i v a s T o l e d o J.: J. Chem. Techn. Biotechn., 89(8), 1219, 2014.
• [8] K o b a l S., B u d i h n a M.V.: Acta Vet., 68, 281, 1999.
• [9] L a f i W. K., A l - Q o d a h Z.: J. Hazard. Mater., 137(1), 489, 2006.
• [10] Ministerstwo Środowiska RP: Krajowy Plan Wdrażania Konwencji Sztokholmskiej w sprawie trwałych zanieczyszczeń organicznych, [electronic document: http://www.mos.gov.pl/g2/big/2012_07/b4e23ee84865f722bf66f792d1036bc3.pdf, date of entry: 16.06.2014]
• [11] S h o r e R.E.: Am. J. Public Health, 85, 4, 474, 1995.
• [12] United States Environmental Protection Agency: Reregistration Eligibility Decision (RED) for MCPA List A Case 0017, [electronic document: http://www.epa.gov/oppsrrd1/REDs/ mcpa_red.pdf, date of entry: 30.06.2014]
• [13] W a l t e r s J.: California Department of Pesticide Regulation, 2,4-dichlorophenoxyacetic Acid, 1999.
• [14] W o ł k o w i c z W.: Państwowy Instytut Geologiczny, [electronic document: http://www.pgi.gov.pl/pl/ochrona-srodowiska-uslugi/583-mogilniki-technologia-likwidacji-i-rekultywacji.html, date of entry: 30.06.2014]