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2016 | 25 | 5 |
Tytuł artykułu

Differences in the uptake of Mn, Zn, and Cu by Hordeum vulgare L. following applications of MCPA-based herbicides and their Ionic liquid forms

Autorzy
Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The aim of this study was to examine the effect of spraying two herbicidal ionic liquid (HIL) forms of MCPA – namely Ethoquad O-12 and didecyldimethylammonium (a cation) and MCPA (an anion) – on the uptake of Mn, Zn, and Cu by spring barley (Hordeum vulgare L.). The total elemental contents of the aboveground parts of the spring barley were measured using flame atomic absorption spectroscopy 24 and 72h after fields were sprayed. The data was compared to controls that consisted of the corresponding treatments using a commercial formulation of MCPA as a salt or ester. The field studies revealed lower contents of Mn, Zn, and Cu in the material after use of commercial formulation compared to HILs. This clean technology provides the means to reduce toxic waste from an industrial chemical process and increase its efficiency in terms of weed control by increasing the absorption rate of macro-and microelements.
Słowa kluczowe
Wydawca
-
Rocznik
Tom
25
Numer
5
Opis fizyczny
p.1931-1936,fig.,ref.
Twórcy
autor
  • Institute of Plant Protection – National Research Institute, Poznan 60-318, Poland
Bibliografia
  • 1. KOBYŁECKA J., SKIBA E. The Effect of Phenoxyacetic Herbicides on the Uptake of Copper, Zinc and Manganese by Triticum Aestivum L. Polish J. of Environment. Stud. 17, 895, 2008.
  • 2. EKER S., OZTURK L., YAZICI A., ERENOGLU B., ROMHELD V., CAKMAK I. Foliar-applied glyphosate substantially reduced uptake and transport of iron and manganese in sunflower (Helianthus annuus L.) plants. Agric. Food Chem. 54, 10019, 2006.
  • 3. LANE M., LORENZ N., SAXENA J., RAMSIER C., DICK R.P. The effect of glyphosate on soil microbial activity, microbial community structure, and soil potassium. Pedobiologia 55, 335, 2012.
  • 4. BOTT S., TESFAMARIAM T., CANDAN H., CAKMAK I., ROMHELD V., NEUMANN G. Glyphosate-induced impairment of plant growth and micronutrient status in glyphosate-resistant soyabean (Glycine max L.). Plant and Soil 312, 185, 2008.
  • 5. CAKMAK I., YAZICI A., TUTUS Y., OZTURK L. Glyphosate reduced seed and leaf concentrations of calcium, manganese, magnesium, and iron in non-glyphosate resistant soybean. Europ. J. Agronomy 31, 114, 2009.
  • 6. CAETANO M.S., RAMALHO T.C., BORTEL D.F., CUNHA E., MELLO W.C. Understanding the inactivation process of organophosphorus herbicides: a DFT study of glyphosate metallic complexes with Zn2+, Ca2+, Mg2+, Cu2+, Co3+, Fe3+, Cr3+ and Al3+. Int. Journal of Quant. Chem. 112, 2752, 2012.
  • 7. PRAMANIK A., ABBINA S., DAS G. Molecular, supramolecular structure and catalytic activity of transition metal complexes of phenoxy acetic acid derivatives. Polyhedron 18, 5225, 2007.
  • 8. KOBYŁECKA J., PTASZYNSKI B., ROGACZEWSKI R., TUREK A. Phenoxyalkanoic acid complexes. Part I. Complexes of lead(II), cadmium(II) and copper(II) with 4-chloro-2-methylphenoxyacetic acid (MCPA). Thermochimica Acta 407, 25, 2003.
  • 9. KOBYŁECKA J., TUREK A., SIEROŃ L. Phenoxyalkanoic acid complexes. Part II. Complexes of selected bivalent metals with 2,4-dichlorophenoxyacetic acid (2,4D) and 2-(2,4-dichlorophenoxy)propionic acid (2,4DP). Thermochimica Acta 482, 49, 2009.
  • 10. GRZESIAK P., MOTAŁA R., GROBELA M., SCHROEDER G. Synergizm metali ciężkich ze środkami ochrony roślin. Prog. Plant Prot. 47, 4, 2007.
  • 11. TUREK A., KOBYŁECKA J., PTASZYŃSKI B. Complexes of dicamba with cadmium(II), copper(II), mercury(II), lead(II) and zinc(II). Synthesis and properties. J. Thermal Anal. Calorimetry 78, 513, 2004.
  • 12. [EFSA http://www.efsa.europa.eu/en/topics/topic/pesticides; Directive 2009/128/EC http://eur-lex.europa.eu/Lex-UriServ/LexUriServ.do?uri=OJ:L:2009:309:0071:0086:en:PDF; Regulation (EC) No 1107/2009 http://eur-lex.europa.eu/LexUriServ/ LexUriServ.do?uri =OJ:L:2009:309:0001:0050:EN:PDF;
  • 13. PERNAK J., SYGUDA A., JANISZEWSKA D., MATERNA K., PRACZYK T. Ionic liquids with herbicidal anions. Tetrahedron 67, 4838, 2011.
  • 14. PERNAK J., SYGUDA A., MATERNA K., JANUS E., KARDASZ P., PRACZYK T. 2,4-D based herbicidal ionic liquids. Tetrahedron 68, 4267, 2012.
  • 15. KORDALA-MARKIEWICZ R., RODAK H., MARKIEWICZ B., WALKIEWICZ F., SZNAJDROWSKA A., MATERNA K., MARCINKOWSKA K., PRACZYK T., PERNAK J. Phenoxy herbicidal ammonium ionic liquids. Tetrahedron 70, 4784,2014.
  • 16. ERNAK J., NIEMCZYK M., ZAKROCKA K., PRACZYK T. Herbicidal ionic liquid with dual-function. Tetrahedron 69, 8132, 2013.
  • 17. COJOCARU O.A., SHAMSHINA J.L., GURAU G., SYGUDA A., PRACZYK T., PERNAK J., ROGERS R.D. Ionic liquid forms of the herbicide dicamba with increased efficacy and reduced volatility. Green Chem. 15, 2110, 2013.
  • 18. DING G., LIU Y., WANG B., PUNYAPITAK D., GUO M., DUAN Y., LI J., CAO Y. Preparation and characterization of fomesafen ionic liquids for reducing the risk to the aquatic environment. New J. Chem. 38, 5590, 2014.
  • 19. POLIT J.T., PRACZYK T., PERNAK J., SOBIECH Ł., JAKUBIAK E., SKRZYPCZAK G. Inhibition of germination and early growth of rape seed (Brassica napus L.) by MCPA in anionic and ester form. Acta Physiol. Plant 36, 699, 2014.
  • 20. KABATA-PENDIAS A., PENDIAS H. Biogeochemistry of Trace Elements, 2nd ed; PWN: Warsaw, 1, 1999 [in Polish].
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.agro-668b41af-21ba-4016-9319-dec0a166f632
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