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2015 | 24 | 1 |

Tytuł artykułu

Effective pharmaceutical wastewater degradation via SCWO with ethylene glycol

Autorzy

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
Pharmaceutical wastewaters are generated through complex manufacturing processes that contain a variety of organic and inorganic constituents, and are usually characterized by a high concentration of chemical oxygen demand (COD), suspended solids, dissolved solids (salts), toxicity, and refractory compounds. Therefore, it must be treated. The treatment of a pharmaceutical wastewater (PWW) using the supercritical water oxidation (SCWO) method was investigated to improve the degradation of the complex-mixture of organic compounds present in the wastewater. The effects of H₂O₂ dosage, reaction time, temperature, initial COD, and concentration of ethylene glycol on COD removal were studied with laboratory bench-scale experiments. The results indicated that the removal process was more effective under experimental conditions. Adding ethylene glycol accelerates the destruction of pharmaceutical wastewater. The best COD removal of pharmaceutical wastewater reached 97.8%. This investigation will provide a fundamental method for developing a pretreatment method of industrial pharmaceutical wastewater with flexibility, simplicity and high activity

Słowa kluczowe

Wydawca

-

Rocznik

Tom

24

Numer

1

Opis fizyczny

p.249-252,fig.,ref.

Twórcy

autor
  • College of Resources and Environment, Southwest University, PRC, 400000 China

Bibliografia

  • 1. DEEGAN A.M., SHAIK B., NOLAN N., URELL K., OELGEMÖLLER M., TOBIN J., MORRISEY A. Treatment options for wastewater effluents from pharmaceutical companies. Environ. Sci. Technol., 8, 649, 2011.
  • 2. CHATZITAKIS A., BERBERIDOU C., PASPALTSIS I., KYRIAKOU G., SKLAVIADIS T., POULIOS I. Photocatalytic degradation and drug activity reduction of Chloramphenicol. Water Res., 42, 386, 2008.
  • 3. FATTA-KASSINOS D., MERIC S., NIKOLAOU A. Pharma-ceutical residues in environmental waters and waste-water: current state of knowledge and future research. Anal. Bioanal. Chem., 399, 251, 2011.
  • 4. SCHROEDER H.F. Substance-specific detection and pursuit of non-eliminable compounds during biological treatment of waste water from the pharmaceutical industry. Waste Manage., 19, 111, 1999.
  • 5. VERLICCHI P., AUKIDY M.A., ZAMBELLO E. Occurrence of pharmaceutical compounds in urban wastewater: Removal, mass load and environmental risk after a secondary treatment-A review. Sci. Total Environ., 429, 123, 2012.
  • 6. ZIYLAN A., INCE N.H. The occurrence and fate of anti-inflammatory and analgesic pharmaceuticals in sewage and fresh water: treatability by conventional and non-conventional processes. J. Hazard. Mater., 187, 24, 2011.
  • 7. KÜMMERER K. The presence of pharmaceuticals in the environment due to human use – present knowledge and future challenges. J. Environ. Manage., 90, 2354, 2009.
  • 8. CHELLIAPAN S., WILBY T., YUZIR A., SALLIS P.J. Influence of organic loading on the performance and microbial community structure of an anaerobic stage reactor treating pharmaceutical wastewater. Desalination, 271, 257, 2011.
  • 9. RAO A.G., NAIDU G.V., PRASAD K.K., RAO N.C., MOHAN S.V., JETTY A., SARMA P.N. Anaerobic treatment of wastewater with high suspended solids from a bulk drug industry using fixed film reactor (AFFR). Bioresour. Technol., 96, 87, 2005.
  • 10. ENICK O., MOORE M. Assessing the Assessments: Pharmaceuticals in the Environment. Environ. Impact. Assess., 27, 707, 2007.
  • 11. KLAVARIOTI M., MANTZAVINOS D., KASSINOS D. Removal of residual pharmaceuticals from aqueous system by advanced oxidation processes. Environ. Int., 35, 402, 2009.
  • 12. MIZUNO T., GOTO M., KODOMA A., HIROSE T. Supercritical water oxidation of a model municipal solid waste. Ind. Eng. Chem. Res., 39, 2807, 2000.
  • 13. MARTINO C.J., SAVAGE P.E. Total Organic Carbon Disappearance Kinetics for the Supercritical Water Oxidation of Monosubstituted Phenols. Environ. Sci. Technol., 33, 1911, 1999.
  • 14. PORTELA J. R., NEBOT E., MARTINEZ DE LA OSSA E. Generalized kinetic models for supercritical water oxidation of cutting oil wastes. J. Supercrit. Fluids, 21, 135, 2001.
  • 15. VERIANSYAH B., PARK T.J., LIMB J.S., LEE Y.W. Supercritical water oxidation of wastewater from LCD manufacturing process: kinetic and formation of chromium oxide nanoparticles. J. Supercrit. Fluids, 34, 51, 2005.
  • 16. PLOEGER, J.M., GREEN, W.H., TESTER, J.W. Co-oxidation of methylphosphonic acid and ethanol in supercritical water: II: Elementary reaction rate model. J. Supercrit. Fluids, 39, 239, 2006.
  • 17. SAVAGE P.E., YU J.L., STYLSDKI N., BROCK E.E. Kinetics and mechanism of methane oxidation in supercritical water. J. Supercrit. Fluids, 12, 141, 1998.
  • 18. BROCK E.E., SAVAGE P.E., BARKER J.R. A reduced mechanism for methanol oxidation in supercritical water. Chem. Eng. Sci., 53, 857, 1998.
  • 19. SAVAGE P.E., ROVIRA J., STYLSKI N., MARTINO C.J. Oxidation kinetics for methane/methanol mixtures in supercritical water. J. Supercrit. Fluids, 7, 155, 2000.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

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