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2019 | 28 | 5 |
Tytuł artykułu

Evaluating forest waste on adsorption of Cd(II) from aqueous solution: equilibrium and thermodynamic studies

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The aim of this work was to investigate the adsorption potential of Uludag fir (Abies nordmanniana subsp. bornmülleriana Mattf.) on cadmium removal using batch experiments. The effect of parameters such as initial metal concentration, initial pH, biosorbent dosage, stirring speed, contact time and temperature was examined. The Langmuir and Freundlich models were applied to describe the equilibrium isotherms, and the biosorption process followed the Langmuir adsorption isotherms model with high coefficients of correlation at different temperatures. The kinetics of the sorption were analysed using the pseudo first-order and pseudo second-order kinetic models. The pseudo second-order kinetic model fit well in correlation with the experimental results. Moreover, the evaluated thermodynamic parameters (ΔG⁰, ΔH⁰, ΔS⁰) showed that the sorption process was feasible, spontaneous and endothermic in nature. This study showed that Uludag fir (Abies nordmanniana subsp. bornmülleriana Mattf.) can be used as an effective and ecologically friendly biosorbent for removal of Cd(II) from aqueous solutions.
Słowa kluczowe
Wydawca
-
Rocznik
Tom
28
Numer
5
Opis fizyczny
p.3829-3836,fig.,ref.
Twórcy
autor
  • Department of Environmental Engineering, Faculty of Engineering, Bartin University, Kutlubey Campus, Bartin, Turkey
autor
  • Department of Environmental Engineering, Faculty of Engineering, Bartin University, Kutlubey Campus, Bartin, Turkey
autor
  • Department of Forest Engineering, Faculty of Forestry, Bartin University, Agdaci Campus, Bartin, Turkey
autor
  • Department of Environmental Engineering, Faculty of Engineering, Bartin University, Kutlubey Campus, Bartin, Turkey
Bibliografia
  • 1. HEGAZI H.A. Removal of heavy metals from wastewater using agricultural and industrial wastes as adsorbents. Housing and Building National Research Center, 9 (3), 276, 2013.
  • 2. RATHORE N.S., LEOPOLD A., PABBY A.K., FORTUNY A., COLL M.T., SASTRE A.M. Extraction and permeation studies of Cd(II) in acidic and neutral chloride media using Cyanex 923 on supported liquid membrane. Hydrometallurgy, 96, 81, 2009.
  • 3. WANG B., GAO B., WAN Y. Entrapment of ball-milled biochar in Ca-alginate beads for the removal of aqueous Cd(II). Journal of Industrial and Engineering Chemistry, 61, 161, 2018.
  • 4. CHENG Q., HUANG Q., KHAN S., LIU Y., LIAO Z., LI G., OK Y.S. Adsorption of Cd by peanut husks and peanut husk biochar from aqueous solutions. Journal of Ecological Engineering, 87, 240, 2016.
  • 5. NGUYEN T.A.H., NGO H.H., GUO W.S., ZHANG J., LIANG S., YUE Q.Y., Li Q., NGUYEN T.V. Applicability of agricultural waste and biproducts for adsorptive removal of heavy metals from wastewater. Bioresource Technology, 148, 574, 2013.
  • 6. KUMAR P.S., RAMAKRISHNAN K., KIRUPHA S.D., SIVANESAN S., Thermodynamic and kinetic studies of cadmium adsorption from aqueous solution onto rice husk. Brazilian Journal of Chemical Engineering, 27 (2), 347, 2010.
  • 7. TU Y.J., YOU C.F., CHANG C.K. Kinetics and thermodynamics of adsorption for Cd on green manufactured nano-particles. Journal of Hazardous Materials, 235, 116, 2012.
  • 8. CUTILLAS-BARREIRO L., PARADELO R., IGREXAS-SOTO A., NUNEZ-DELGADO A., FERNANDEZ-SANJURJO M.J., ALVAREZ-RODRIGUEZ E., GARROTE G., NOVOA-MUNOZ J.C., ARIAS-ESTEVEZ M. Valorization of biosorbent obtained from a forestry waste: Competitive adsorption, desorption and transport of Cd, Cu, Ni, Pb and Zn. Ecotoxicology and Environmental Safety, 131, 118, 2016.
  • 9. BOZIC D., STANKOVIC V., GORGIEVSKI M., BOGDANOVIC, G., KOVACEVIC R. Adsorption of heavy metal ions by sawdust of deciduous trees. Journal of Hazardous Materials, 171, 684, 2009.
  • 10. OFOMAJA A.E., NAIDOO E.B., MODISE S.J., Biosorption of Cu(II) and Pb(II) onto potassium hydroxide treated pine cone powder. Journal of Environmental Management, 91, 1674, 2010.
  • 11. SEN T.K., MOHAMMOD M., MAITRA S., DUTTA B.K. Removal of cadmium from aqueous solution using castor seed hull: a kinetic and equilibrium study. Clean-Soil, Air, Water, 38, 850, 2010.
  • 12. KUMAR P.S., RAMALINGAM S., SATHYASELVABALA V., KIRUPHA S.D., MURUGESAN A., SIVANESAN S. Removal of Cd(II) from aqueous solution by agricultural waste cashew nut shell. Korean Journal of Chemical Engineering, 29, 756, 2012.
  • 13. FAROOQ U., KHAN M.A., ATHAR M., KOZINSKI J.A. Effect of modification of environmentally friendly biosorbent wheat (Triticum aestivum) on the biosorptive removal of cadmium(II) ions from aqueous solution. Chemical Engineering Journal, 171, 400, 2011.
  • 14. KIM N., PARK M., PARK D. A new efficient forest biowaste as biosorbent for removal of cationic heavy metals. Bioresource Technology, 175, 629, 2015.
  • 15. UCUN H., AKSAKAL O., YILDIZ E. Copper(II) and zinc(II) biosorption on Pinus sylvestris L. Journal of Hazardous Materials, 161, 1040, 2009.
  • 16. CHEN Y., WANG H., ZHAO W., HUANG S. Four different kinds of peels as adsorbents for the removal of Cd (II) from aqueous solution: Kinetics, isotherm and mechanism. Journal of the Taiwan Institute of Chemical Engineers, 88, 146, 2018.
  • 17. KULKARNI M.R., REVANTH T., ACHARYA A., BHAT P. Removal of crystal violet dye from aqueous solution using water hyacinth: equilibrium, kinetics and thermodynamics study. Resource-Efficient Technologies, 3, 71, 2017.
  • 18. SMITH J.M. Chemical Engineering Kinetics, 3rd ed.; McGraw-Hill: New York, USA, 310, 1981.
  • 19. UCUN-OZEL H. Biosorption of Cd(II) ions by Nordmann fir cones. Fresenius Environmental Bulletin, 21 (9), 2527, 2012.
  • 20. DENIZ F., KEPEKCI R.A. Bioremoval of malachite green from water sample by forestry waste mixture as potential biosorbent. Microchemical Journal, 132, 172, 2017.
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.agro-38c8e055-2117-497b-ac6d-9ba35ed7f043
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