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2012 | 21 | 3 |
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Determinants of seasonal changes in streamwater chemistry in small catchments with different land use: case study from Poland`s Carpathian Foothills

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Our paper aims at identifying factors that determine seasonal changes in streamwater chemistry in three catchments with different land use (woodland, agricultural, mixed-use) in the Carpathian Foothills in southern Poland. The study involved weekly and biweekly water sampling in the 2003 and 2004 hydrological years and the analysis of specific conductivity (SC), pH, main ions, and nutrients. R-mode factor analysis was used to identify four factors: (i) streamflow, (ii) climate seasonality, (iii) water circulation, and (iv) nitrification processes. Despite the fact that the same environmental factors were identified in all three catchments, some factors produce a different type of ion response in different types of catchments. The streamflow factor produces the same changes in geologically controlled parameters (SC, main ions) in all catchments but different changes in nutrient concentrations in the woodland and agricultural catchments. In the woodland catchment, nutrients come primarily from diffuse sources (soil flushing), while in the agricultural catchment, nutrients come primarily from point sources (sewage) as result of unregulated wastewater management. The climate factor primarily controls the concentrations of nutrients. High temperatures during the vegetation season usually correlate with increases in nutrient concentrations, especially that of PO₄³⁻. This atypical phenomenon is seldom reported in the literature, especially in relation to woodland catchments. The third factor is associated with water circulation in the catchment under different hydrological conditions - during flood events and during low-flow periods. The fourth factor is most likely associated with nitrification processes.
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  • Institute of geography and Spatial Management, Department of Hydrology, Jagiellonian University, Gronostajowa 7, 30-387 Krakow, Poland
  • 1. BURNS D. A., MURDOCH P. S., LAWRENCE G. B., MICHEL R. L. Effect of groundwater springs on NO₃⁻ concentrations during summer in Catskill Mountain streams. Wat. Resour. Res. B, 1987,1998.
  • 2. CAMERON, E. M. Hydrogeochemistry of the Fraser River, British Columbia: seasonal variation in major and minor components. J. Hydrol. 182, 206,1996.
  • 3. JOHNSON N. M., LIKENS G. E., BORMANN F. H., FISHER D. W., PIERCE R. S. A working model for the variation in stream water chemistry at the Hubbard Brook Experimental Forest, New Hempshire. Wat. Resour. Res. 5, 1353,1969.
  • 4. RICE K. C., BRICKER O. P. Seasonal cycles of dissolved constituents in streamwater in two forested catchments in the mid-Atlantic region of the eastern USA. J. Hydrol. 170, 137,1995.
  • 5. MUSCUTT A. D., WITHERS P. J. A. The phosphorus content of rivers in England and Wales. Water Res. 30, 1258,1996.
  • 6. EDWARDS A.M.C. The variation of dissolved constituents with discharge in some Norfolk Rivers. J. Hydrol. 18, 219, 1973.
  • 7. RINELLA F. A., JANET M. L. Seasonal and spatial variability of nutrients and pesticydes in streams of the Willamette Basin, Oregon, 1993-95. U.S. Geological Survey: Portland, pp. 59,1998.
  • 8. PIONKE H. B., GBUREK W. J., SCHNABEL R. R, SHARPLEY A. N., ELWINGER G. F. Seasonal flow, nutrient concentrations and loading patterns in stream flow draining an agricultural hill-land watershed. J. Hydrol. 220, 62, 1999.
  • 9. ARHEIMER B., ANDERSSON L., LEPISTÖ A. Variation of nitrogen in forest streams - influences of flow, seasonality and catchment characteristics. J. Hydrol. 179, 281,1996.
  • 10. BETTON C, WEBB B. W., WALLING D. E. Recent trends in NO₃-N concentrations and loads in British rivers. IAHS Publ. 203, 169,1991.
  • 11. BHANGU I., WHITFIELD P. H. Seasonal and long-term variations in water quality of the Skeena River at Usk, British Columbia. Water Res. 31, 2187,1997.
  • 12. CLARK M. J., CRESSER M. S., SMART R., CHAPMAN P. J., EDWARDS A. C. The influence of catchment characteristics on the seasonality of carbon and nitrogen species concentrations in upland rivers of Northern Scotland. Biogeochemistry 68, 1, 2004.
  • 13. EDWARDS A. C., CREASEY J., CRESSER M. S. Factors influencing nitrogen inputs and outputs in two Scottish upland catchments. Soil Use Manage 1, 83,1985.
  • 14. HOLLO WAY J. M, DAHLGREN R. A. Seasonal and eventscale variations in solute chemistry for four Sierra Nevada catchments. J. Hydrol. 250, 106, 2001.
  • 15. LEPISTÖ A. Increased leaching of nitrate at two forested catchments in Finland over a period of 25 years. J. Hydrol. 171, 103, 1995.
  • 16. MILLER J. D., HIRST D. Trends in concentrations of solutes in an upland catchment in Scotland. Sci. Total Environ. 216, 77, 1998.
  • 17. MURDOCH P. S., STODDARD J. L. The role of nitrate in the acididification of streams in the Catskill Mountains of New York. Wat. Resour. Res. 28, 2707,1992.
  • 18. REYNOLDS B., EMMETTB. A., WOODS C. Variations in stream water nitrate concentrations and nitrogen budgets over ten years in a headwater catchment in mid-Wales. J. Hydrol. 136, 155,1992.
  • 19. SULLIVAN A. B., DREVER J. I. Spatiotemporal variability in stream chemistry in a high-elevation catchment affected by mine drainage. J. Hydrol. 252, 240, 2001.
  • 20. TAYLOR A. W., EDWARDS W. M., SIMPSON E. C. Nutrients in streams draining woodland and farmland near Coshocton, Ohio. Wat. Resour. Res. 7, 81,1971.
  • 21. FELLER M. C., KIMMINS J. P. Chemical characteristic of small streams near Haney in Southwestern British Columbia. Wat. Resour. Res. 15, 247,1979.
  • 22. PIÑOL J., ÁVILA A., RODA F. The seasonal variation of streamwater chemistry in three forested Mediterranean catchments. J. Hydrol. 140, 119, 1992.
  • 23. LYNCH J. A., CORBETT E. S. Hydrologie control of sulfate mobility in a forested watershed. Wat. Resour. Res. 25, 1695,1989.
  • 24. EVANS C. D., DAVIES T. D., WIGINGTON P. J., TRANTER M., KRETSER W. A. Use of factor analysis to investigate processes controlling chemical composition of four streams in the Adirondack Mountains, New York. J. Hydrol. 185, 297, 1996.
  • 25. MCDOWELL T. R., OMERNIK J. M. Nonpoint source - stream nutrient level relationships: a nationwide study. EPA- 600/3-79-103,1979.
  • 26. OLEWICZ Z. R. Tectonic of the Bochenska unit and the marginal zone of the Silesian unit between Raba and Uszwica rivers. Acta Geol Polonica 23, 701, 1973 [In Polish],
  • 27. SKIBA S., DREWNIK M., KLIMEK M., SZMUC R. Soil cover in the marginal zone of the Carpathian Foothills between the Raba and Uszwica rivers. Pr. Geogr. IGUJ 103, 125,1998.
  • 28. PIETRZAK M. System of water and wastewater management in the Wiśnickie Foothills' catchment, in: Żelazny M. (Ed.), Biogenic compounds in precipitation water, streamwater and groundwater in catchments with different land uses in the Wiśnickie Foothills, southern Poland. IGiGP U J, Kraków, pp. 55-63, 2005 [In Polish],
  • 29. ŚWIĘCHOWICZ J. The influence of plant cover and land use on slope-channel decoupling in a foothill catchment: a case study from the Carpathian Foothills, Southern Poland. Earth Surf. Proc. Land. 27, 463, 2002.
  • 30. CHEŁMICKI W., BAŚCIK M., POCIASK-KARTECZKA J. Water balance of the foothill drainage basins of Stara Rzeka and Dworski Potok in 1987-1995, in: Kaszowski L. (Ed.), Dynamics and anthropogenic transformation of the natural environment of the edge zone of the Carpathians between the Raba and Uszwica rivers. IGUJ: Kraków, pp. 171-183,1995 [In Polish],
  • 31. ŻELAZNY M. (Ed.) Biogenic compounds in precipitation water, streamwater and groundwater in catchments with different land uses in the Wiśnickie Foothills, southern Poland. IGiGP U J, Kraków, pp. 216, 2005 [In Polish],
  • 32. SIWEK J. P., ŻELAZNY M., CHEŁMICKI W. Annual changes in the chemical composition of stream water in small catchments with different land-use (Carpathian Foothills, Poland). Soil and Water Res. 3, 129, 2008.
  • 33. DINGMAN S. L. Physical hydrology. Prentice Hall: Upper Saddle River, NJ, pp. 646, 2002.
  • 34. WANIELISTA M., KERSTEN R., EAGLIN R. Hydrology: Water Quantity and Quality Control. John Wiley and Sons, New York, pp. 592,1997.
  • 35. DAVIS J. C. Statistics and data analysis in geology. John Wiley & Sons: New York, pp. 550,1973.
  • 36. DREVER J. I. The geochemistry of natural water. Surface and groundwater environments, 3rd ed. Prentice Hall: Upper Saddle River, NJ, pp. 436,1997.
  • 37. SHAW G., WHEELER D. Statistical techniques in geographical analysis, 2nd ed. David Fulton Publishers, London, pp. 359,1997.
  • 38. BERNAL S., BUTTURINI A., SABATER F. Variability of DOC and nitrate responses to storms an a small Mediterranean forested catchment. Hydrol. Earth Syst. Sci. 6, 1031,2002.
  • 39. CLEVELAND W. S. Robust locally weighted regression and smoothing scatterplots. J. Am. Stat. Assoc. 74, 829, 1979.
  • 40. CLEVELAND W. S. The Elements of Graphing Data. Wadsworth: Monterey, pp. 321,1985.
  • 41. HELSEL D.R., HIRSCH R.M. Statistical methods in water resources. Techniques of Water-Resources Investigations. Book 4. Chapter A3. U.S. Geological Survey, pp. 522, 2002.
  • 42. HIRSCH R. M., ALEXANDER R. B., SMITH R. A. Selection of methods for the detection and estimation of trends in water quality. Wat. Resour. Res. 27, 803,1991.
  • 43. PEKÁROVÁ P., MIKLÁNEK P., KONÍČEK A., PEKÁR J. Water quality in experimental basins. SVH Publ.: Bratislava, pp. 97,1999.
  • 44. CAISSIE D., POLLOCK T. L., CUNJAK R. A. Variation in stream water chemistry and hydrograph separation in a small drainage basin. J. Hydrol. 178, 137,1996.
  • 45. SIWEK J. P., ŻELAZNY M., CHEŁMICKI W. Influence of catchment characteristics and flood type on relationship between streamwater chemistry and streamflow: case study from Carpathian Foothills in Poland. Water Air Soil Pollut. 214, 547, 2011.
  • 46. ENVIRONMENT 2010, Central Statistical Office, Warsaw, 2010.
  • 48. ALLAN J. D. Stream ecology. Structure and function of running water. Chapman & Hall: London, pp. 388,1995.
  • 49. FÖLLMI K. B. The phosphorus cycle, phosphogenesis and marine phosphate-rich deposits. Earth Sci. Rev. 40, 50, 1996.
  • 50. DREWNIK M. The effect of environmental conditions on the decomposition rate of cellulose in mountain soils. Geoderma 132, 116, 2006.
  • 51. KAISER K., GUGGENBERGER G., HAUMAIER L., ZECH W. Seasonal variations in the chemical composition of dissolved organic matter in organic forest floor layer leachates of old-growth Scots pine (Pinns sylvestris L.) and European beech (Fagus sylvatica L.) stands in northeastern Bavaria, Germany. Biogeochemistry 55, 103, 2001.
  • 52. SCOTT M. J., JONES M. N., WOOF C., TIPPING E. Concentrations and fluxes of dissolved organic carbon in drainage water from an upland peat system. Environ. Int. 24, 537, 1998.
  • 53. TIPPING E., WOOF C., RIGG E., HARRISON A. F., INESON P., TAYLOR K., BENHAM D., POSKITT J., ROWLAND A. P., BOL R., HARKNESS D. D. Climatic influences on the leaching of dissolved organic matter from upland UK moorland soils, investigated by a field manipulation experiment. Environ. Int. 25, 83,1999.
  • 54. VITOUSEK P. M., REINERS W. A. Ecosystem succession and nutrient retention: a hypothesis. Bioscience 25, 376, 1975.
  • 55. FLESCHNER M. D. Nitrogen fixation in a small subalpine watersheds. PhD dissertation. University of California: Davis, 1975.
  • 56. COATS R. N., GOLDMAN CH. R. Patterns in nitrogen transport in streams of the Lake Tahoe basin, California- Nevada. Wat. Resour. Res. 37, 405, 2001.
  • 57. LEONARD R. L., KAPLAN L. A., ELDER J. F., COATS R. N., GOLDMAN C. R. Nutrient transport in surface runoff from a subalpine watershed, Lake Tahoe Basin, California. Ecol. Monogr. 49, 281,1979.
  • 58. EVANS CH., DAVIES T. D. Causes of concentration/discharge hysteresis and its potential as a tool for analysis of episode hydrochemistry. Wat. Resour. Res. 34, 129, 1998.
  • 59. JOHNSON A. H„ BOULD1N D. R, GOYETTE E. A., HEDGES A. M. Phosphorus loss by stream transport from a rural watershed: quantities, processes, and sources. J. Environ. Qual. 5, 148, 1976.
  • 60. RIEBE C. S, KIRCHNER J. W., FINKEL R. C. Sharp decrease in long-term chemical weathering rates along an altitudinal transect. Earth Planet. Sc. Lett. 218, 421, 2004.
  • 61. RIEBE Q. S., KIRCHNER J. W., FINKEL R. C. Erosional and climatic effects on long-term chemical weathering rates in granitic landscapes spanning diverse climate regimes. Earth Planet Sc. Lett. 224, 547, 2004.
  • 62. OLLIER C. Weathering, 2nd ed. Longman: London, pp. 270, 1984.
  • 63. WHITE A. F., BLUM A. E. Climatic effects on chemical weathering in watersheds - application of mass balance approaches, in: Trudgill S.T. (Ed.), Solute modelling in catchment systems. John Wiley and Sons: London, pp. 102,1995.
  • 64. WHITE A. F., BLUM A. E. Effects of climate on chemical weathering in watersheds. Geochim. Cosmochim. Ac. 59, 1729, 1995.
  • 65. DREVER J.I. The effect of land plants on weathering rates of silicate minerals. Geochim. Cosmochim. Ac. 58, 2325,1994.
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