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2017 | 26 | 6 |

Tytuł artykułu

Synthesis of the sodalite by geopolymerization process using coal fly ash

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
This study investigated the influence of alkali activation process conditions on the amount and types of zeolites in the resultant geopolymers. The products were formed during the alkaline activation of coal fly ash with the use of aluminium and sodium hydroxide solution. Geopolymers were cured at 80ºC for 24 h. The effects of reaction systems’ constitution (expressed as SiO₂/Al₂O₃ and Al₂O₃ /Na₂O molar ratios) on the phase composition and structure of obtained products were determined. The results indicated that the products obtained from such hydrothermal treatment demonstrated the characteristics of zeolite-like materials – sodalite. By using the appropriate composition of the initial solution (sufficiently high concentration of NaOH and aluminum carrier), it is possible to synthesize the sodalite phase efficiently in an amorphous matrix.

Słowa kluczowe

Wydawca

-

Rocznik

Tom

26

Numer

6

Opis fizyczny

p.2611-2617,fig.,ref.

Twórcy

autor
  • Synthesis of the Sodalite by Geopolymerization Process Using Coal Fly Ash
autor
  • Synthesis of the Sodalite by Geopolymerization Process Using Coal Fly Ash
autor
  • Synthesis of the Sodalite by Geopolymerization Process Using Coal Fly Ash

Bibliografia

  • 1. DAVIDOVITS J. Geopolymer Chemistry and Applications. Geopolymer Institute, 2008.
  • 2. DAVIDOVITS J. Geopolymers: Inorganic polymeric new materials. J Therm Anal, 37, 1633, 1991.
  • 3. KRÓL M., MINKIEWICZ J., MOZGAWA W. IR spectroscopy studies of zeolites in geopolymeric materials derived from kaolinite. J Mol Struct, 1126, 200, 2016.
  • 4. TANG Q., HE Y., WANG Y.P., WANG K.T., CUI X.M. Study on synthesis and characterization of ZSM-20 zeolites from metakaolin-based geopolymers. Appl Clay Sci, 129, 102, 2016.
  • 5. ZHANG J., HE Y., WANG Y.P., MAO J., CUI X.M. Synthesis of a self-supporting faujasite zeolite membrane using geopolymer gel for separation of alcohol/water mixture. Mater Lett, 116, 167, 2014.
  • 6. XU M.X., HE Y., WANG Y.P., CUI X.M. Preparation of a non-hydrothermal NaA zeolite membrane and defect elimination by vacuum-inhalation repair method. Chem Eng Sci, 158, 117, 2017.
  • 7. LEE N.K., KHALID H.R., LEE H.K. Synthesis of mesoporous geopolymers containing zeolite phases by a hydrothermal treatment. Microporous Mesoporous Mater, 229, 22, 2016.
  • 8. ÁLVAREZ-AYUSO E., QUEROL X., PLANA F., ALASTUEY A., MORENO N., IZQUIERDO M., FONT O., MORENO T., DIEZ S., VÁZQUEZ E., BARRA M. Environmental, physical and structural characterization of geopolymer matrixes synthesised from coal (co-) combustion fly ashes. J Hazard Mater, 154, 175, 2008.
  • 9. LUO J., ZHANG H., YANG J. Hydrothermal synthesis of sodalite on alkali-activated coal fly ash for removal of lead ions. Procedia Environ Sci, 31, 605, 2016.
  • 10. QUEROL X., MORENO N., UMAÑA J.C., ALASTUERY A., HERNÁNDEZ E., LÓPEZ-SOLER A., PLANA F. Synthesis of zeolites from coal fly ash: an overview. I J Coal Geol, 50, 413, 2002.
  • 11. MAMEDOVA G.A. Hydrothermal synthesis of natrolite-type zeolite in the natural halloysite-obsidian system. Glass Phys Chem, 40, 380, 2014.
  • 12. KRÓL M., MOZGAWA W., MORAWSKA J., PICHÓR W. Spectroscopic investigation of hydrothermally synthesized zeolites from expanded perlite. Microporous Mesoporous Mater, 196, 216, 2014.
  • 13. RATTANASAKA U., CHINDAPRASIRT P. Influence of NaOH solution on the synthesis of fly ash geopolymer. Miner Eng, 2 (12) 1073, 2009.
  • 14. KOMLJENOVIĆ M., BAŠČAREVIĆ Z., BRADIĆ V. Mechanical and microstructural properties of alkali-activated fly ash geopolymers. J Hazard Mater, 181, 35, 2010.
  • 15. ERDOĞDU K., TÜRKER P. Effects of fly ash particle size on strength of Portland cement fly ash mortars. Cement Concrete Res, 28 (9), 1217, 1998.
  • 16. MOZGAWA W., KRÓL M., DYCZEK J., DEJA J. Investigation of the coal fly ashes using IR spectroscopy. Spectrochim Acta A, 132, 889, 2014.
  • 17. DUXSON P., PROVIS J.L., LUKEY G.C., MALLICOAT S.W., KRIVEN W.M., VAN DEVENTER J.S.J. Understanding the relationship between geopolymer composition, microstructure and mechanical properties. Colloid Surface A, 269, 47, 2005.
  • 18. FERNÁNDEZ-JIMÉNEZ A., PALOMO A. Mid-infrared spectroscopic studies of alkali-activated fly ash structure. Microporous Mesoporous Mater, 86, 207, 2005.
  • 19. SITARZ M. The structure of simple silicate glasses in the light of middle infrared spectroscopy studies. J Non-Cryst Solids 357, 1603, 2011.
  • 20. KRÓL M., MOZGAWA W., MORAWSKA J., PICHÓR W. Spectroscopic investigation of hydrothermally synthesized zeolites from expanded perlite. Microporous Mesoporous Mater, 196, 216, 2014.
  • 21. SCOTT F.A., GOLDENSON J., WIBERLEY S.E., BAUER W.H. Infrared spectra of aluminum soaps and soap-hydrocarbon gels. J Phys Chem, 58 (1), 61, 1954.
  • 22. MOZGAWA W. The relation between structure and vibrational spectra of natural zeolites. J Mol Struct, 596, 129, 2001.
  • 23. MIKUŁA A., KRÓL M., KOLEŻYŃSKI A. Experimental and theoretical spectroscopic studies of Ag-, Cd- and Pb-sodalite. J Mol Struct, 1126, 110, 2016.
  • 24. CHERNYSHOVA I.V., PONNURANGAM S., SOMASUNDARAN P. Linking interfacial chemistry of CO₂ to surface structures of hydrated metal oxide nanoparticles: hematite. Phys Chem Chem Phys, 15, 6953, 2013.
  • 25. PACHECO-TORGAL F., CASTRO-GOMES J., JALALI S. Alkali-activated binders: a review part I, historical background, terminology, reaction mechanisms and hydration products. J Constr Build Mater, 22, 1305, 2008.
  • 26. ABDULLAH M.M.A., HUSSIN K., BNHUSSAIN M., ISMAIL K.N., IBRAHIM W.M.W. Mechanism and chemical reaction of fly ash geopolymer cement – a review. Int J Pure Appl Sci Technol, 6 (1), 35, 2011.
  • 27. RATTANASAK U., CHINDAPRASIRT P. Influence of NaOH solution on the synthesis of fly ash geopolymer. Miner Eng, 22, 1073, 2009.
  • 28. NATH S.K., MAITRA S., MUKHERJEE S., KUMAR S. Microstructural and morphological evolution of fly ash based geopolymers. Constr Build Mater, 111 (3), 758, 2016.
  • 29. SATTERFIELD C.N. Heterogeneous catalysis in practice. McGraw-Hill, New York, 1980.
  • 30. RUTHVEN D.M. Charaacterization of zeolites by sorption capacity measurments. In: Verified syntheses of zeolitic materials, Robson H., Editor, Elsavier:, 61, 2011.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

bwmeta1.element.agro-28dd1d8a-d14c-4bd7-b8f7-a62d938ee01e
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