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2012 | 21 | 6 |
Tytuł artykułu

Chemical degradation of forest soil as a result of polymetallic ore mining activities

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The results of research conducted in the surroundings of a former polymetallic mine near the town of Zlaté Hory, North Moravia, Czech Republic, are presented. A by-product of the ore flotation technique was 6.8 million tons of metalliferous tailings. The adjacent forest area is contaminated by wind-blown pyritic dust particles. The experimental profile was located in a spruce monoculture down wind of the tailings. Samples of soil were taken at 50 m intervals. Ten soil pits were dug and soil samples were taken from the artificial top layer of deposited tailing dust, as well as from the Ah and Bw horizons. Soil samples were analyzed using AAS in order to obtain total heavy metal content of Cu, Zn, Pb, Cd and soluble forms of Al and Fe. The content of accessible nutrients (Mg, Ca, and K) was measured, as well as the content of organic carbon and the ratio of phosphorus retention. Both active and exchangeable soil pH was measured. Our results showed that the main problem is not heavy metal contamination per se, but rather severe acidification. The oxidation of pyrite has resulted in a decrease in pH (pH/H2O ranging from 3.1 to 4.1). The final values for Al and Fe solubility fall within either the aluminium or iron buffer ranges. Such severe acidification has led to increased toxic Al mobilization, the serious leaching of mineral nutrients (Mg: <0.05-34 mg·kg⁻¹, Ca: 0.6-244 mg·kg⁻¹, and K: <0.1-108 mg·kg⁻¹), and a high degree of irreversible retention of phosphorus (90-95%).
Słowa kluczowe
Wydawca
-
Rocznik
Tom
21
Numer
6
Opis fizyczny
p.1551-1561,fig.,ref.
Twórcy
autor
  • Department of Ecology and Environmental Sciences, Faculty of Science, Palacky University, tr. Svobody 26, 771 46 Olomouc, Czech Republic
autor
  • Department of Ecology and Environmental Sciences, Faculty of Science, Palacky University, tr. Svobody 26, 771 46 Olomouc, Czech Republic
autor
  • Department of Soil Science, Faculty of Natural Sciences, Comenius University, Mlynska dolina B-2, 842 15 Bratislava, Slovak Republic
Bibliografia
  • 1. SIMA M., DOLD B., FREI L., SENILA M., BALTEANU D., ZOBRIST J. Sulfide oxidation and acid mine drainage formation within two active tailings impoundments in the Golden Quadrangle of the Apuseni Mountains, Romania. J. Hazard. Mater. 189, 624, 2011.
  • 2. AUDRY S., GROSBOIS C., BRIL H., SCHÄFER J., KIERCZAK J., BLANC G. Post-depositional redistribution of trace metals in reservoir sediments of a mining/smeltingimpacted watershed (the Lot River, SW France). Appl. Geochem. 25, 778, 2010.
  • 3. PARVIAINEN A. Tailings Mineralogy, Geochemistry at the abandoned Haveri Au–Cu Mine, SW Finland. Mine Water Environ. 28, 291, 2009.
  • 4. FERREIRE DA SILVA E., CARDOSO FONSECA E., MATOS J.X., PATINHA C., REIS P., SANTOS OLIVEIRA J.M. The effect of unconfined mine tailings on the geochemistry of soils, sediments and surface waters of the Lousal area (Iberian Pyrite Belt, Southern Portugal). Land Degradation and Development 16, 213, 2005.
  • 5. GUNSINGER M.R., PTACEK C.J., BLOWES D.W., JAMBOR J.L. Evaluation of long-term sulfide oxidation processes within pyrrhotite-rich tailings, Lynn Lake, Manitoba. J. Contam. Hydrol. 83, 149, 2006.
  • 6. ALAKANGAS L., ÖHLANDER B., LUNDBERG A. Estimation of temporal changes in oxidation rates of sulphides in copper mine tailings at Laver, Northern Sweden. Sci. Total Environ. 408, 1386, 2010.
  • 7. MALMSTRÖM, M.E., GLEISNER M., HERBERT R.B. Element discharge from pyritic mine tailings at limited oxygen availability in column experiments. Appl. Geochem. 21, 184, 2006.
  • 8. NORDSTROM D.K., SOUTHAM G. Geomicrobiology of sulfide mineral oxidation. In: Banfield J.F., Nealson K.H. (Eds.), Geomicrobiology: Interactions between Microbes and Minerals. Rev. Mineral. 35, 361, 1997.
  • 9. NORDSTROM D.K., ALPERS, C.N. Geochemistry ofacid mine waters. In: Plumlee G.S., Logsdon M.J. (Eds.), The Environmental Geochemsitry of Mineral Deposits. Reviews in Economic Geology 6A, Society of Economic Geologists, pp. 133-160, 1999.
  • 10. JAMBOR J.L. Mineralogy of sulfide-rich tailings and their oxidation products. In: Jambor J.L., Blowes D.W. (Eds.), The Environmental Geochemistry of Sulfide Mine-wastes, Short Course Handbook 22, Mineralogical Association of Canada, May 1994, Waterloo, Ontario, Canada, pp. 59-102, 1994.
  • 11. GLEISNER M., HERBERT R.B. Jr. Sulfide mineral oxidation in freshly processed tailings: batch experiments. J. Geochem. Explor. 76, 139, 2002.
  • 12. SALMON S.U., MALMSTRÖM M.E. Quantification of mineral weathering rates and applicability of rate laws: Laboratory studies of mill tailings. Appl. Geochem. 21, 269, 2004.
  • 13. GLEISNER M. Quantification of mineral weathering rates in sulfidic mine tailings under water-saturated conditions. Stockholm University, Department of Geology and Geochemistry, 2005.
  • 14. LIAO M., XIE X.M. Effect of heavy metals on substrate utilization pattern, biomass, and activity of microbial communities in a reclaimed mining wasteland of red soil area. Ecotox. Environ. Safe. 66, 217, 2007.
  • 15. MITCHELL T.K., NGUYEN A.V., EVANS G.M. Heterocoagulation of chalcopyrite and pyrite minerals in flotation separation. Adv. Colloid Interfac. 114-115, 227, 2005.
  • 16. DUARTE A.C.P., GRANO S.R. Mechanism for the recovery of silicate gangue minerals in the flotation of ultrafine sphalerite. Miner. Eng. 20, 766, 2007.
  • 17. ŠENK B., PÁNEK P. Technical project on liquidation – Removal of ore mining load under the administration of o.z. GEAM Dolni Rožinka. DIAMO, Straž pod Ralskem, 2003, [In Czech].
  • 18. ČERNÍK M. Research on natural geochemical and biochemical processes for the development of technology for remediation after mineral mining. Annual Report 2005, Stage 1. AQUATEST a.s., Praha, 2005, [In Czech].
  • 19. ZBÍRAL J. Soil analyses I – Unified work methods. Central Institute for Supervising and Testing in Agriculture, Brno, 1995, [In Czech].
  • 20. ZBIRAL J. Soil analyses II – Unified work methods. Central Institute for Supervising and Testing in Agriculture, Brno, 1996, [In Czech].
  • 21. BURT R. (Ed.). Soil Survey Laboratory Methods Manual. Soil Survey Investigations Report No. 42. USDA-NRCS. 2004.
  • 22. SZYNKOWSKA M.I., PAWLACZYK A., LEŚNIEWSKA E., PARYJCZAK T. Toxic Metal Distribution in Rural and Urban Soil Samples Affected by Industry and Traffic. Pol. J. Environ. Stud. 18, 1141, 2009.
  • 23. ULRICH B. An Ecosystem Approach to Soil Acidification. In: B. Ulrich B., Sumner M.E. (Eds.): Soil Acidity, Springer Verlag, pp. 28-79, 1991.
  • 24. DOLD B. Basic Concepts in Environmental Geochemistry of Sulfidic Mine-Waste Management. In: Kumar ES (Ed.): Waste Manage., InTech, 173-198, 2010.
  • 25. DUBIKOVA M., CAMBIER P., SUCHA V., CAPLOVICOVA M. Experimental Soil Acidification. Appl. Geochem. 17, 245, 2002.
  • 26. YOUNGER P.L., BANWART S.A., HEDIN R.S. Mine Water: Hydrology, Pollution, Remediation. Kluwer Academic Publishers, Dordrecht, 2002.
  • 27. MERINO A., MACÍAS F., GARCÍA-RODEJA E. Aluminium dynamics in experimentally acidified soils from a humid-temperate region of south Europe. Chemosphere, 36, 1137, 1998.
  • 28. BRUMME R., KHANNA P.K. Stand, Soil and Nutrient Factors Determining the Functioning and Management of Beech Forest Ecosystems: A Synopsis. Brumme R., Khanna P.K. (Eds.): Functioning and Management of European Beech Ecosystems. Ecol. Stud., 208, 459, 2009.
  • 29. DE VRIES W., REINDS G.J., VEL E. Intensive monitoring of forest ecosystems in Europe 2: atmospheric deposition and its impacts on soil solution chemistry. Forest Ecol. Manag. 174, 97, 2003.
  • 30. VÄÄNÄNEN R., KENTTÄMIES K., NIEMINEN M., ILVESNIEMI H. Phosphorus retention properties of forest humus layer in buffer zones and clear- cut areas in southern Finland. Boreal Environment Research 12, 601, 2007.
  • 31. GIESLER R., ANDERSSON T., LÖVGREN L., PERSSON P. Phosphate Sorption in Aluminum- and Iron-Rich Humus Soils. Soil Sci. Soc. Am. J., 69, 77, 2005.
  • 32. GOLEZ, N.V., KYUMA K. Influence of pyrite oxidation and soil acidification on some essential nutrient elements. Aquacult. Eng., 16, 107, 1997.
  • 33. MILLER F.S., KILMINSTER K.L., DEGENS B., FIRNS G.W. Relationship between Metals Leached and Soil Type from Potential Acid Sulphate Soils under Acidic and Neutral Conditions in Western Australia. Water Air Soil Poll., 205, 133, 2010.
  • 34. DIJKSTRA J.J., MEEUSSEN J.C.L., COMANS,R.N.J. Leaching of heavy metals from contaminated soils: an experimental and modelling study. Environ. Sci. Technol., 38, 4390, 2004.
  • 35. MORENO L., NERETNIEKS I. Long-term environmental impact of tailings deposits. Hydrometallurgy, 83, 176, 2006.
  • 36. CARLON C. (Ed.): Derivation methods of soil screening values in Europe. A review and evaluation of national procedures towards harmonization. European Commission, Joint Research Centre, Ispra, 2007.
  • 37. BALLARD T.M., CARTER R.E. Evaluating Forest Stand Nutrient Status. B.C. Ministry of Forests, Victoria. Land Management Report No. 20, 1986.
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Bibliografia
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