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2013 | 63 | 3 |

Tytuł artykułu

Role of Different Bleaching Earths for Sunfl ower Oil in a Pilot Plant Bleaching System

Treść / Zawartość

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
The purpose of present study is to investigate the efficiency of different kinds of Turkish commercial bleaching earth materials for changes in different colour pigment concentrations in neutralized sunfl ower oils. The bleaching experiments were performed in a pilot system under at stable vacuum (50 mmHg) and temperature (100ºC) for 30 min. By examining the changes in chlorophyll, β-carotene and red colour, bleaching process parameters such as type and dosage of the bleaching material were optimised. The sorption characteristics of colour pigments were evaluated using common adsorption isotherms and Scatchard plot analysis. Ads-3 acid-activated earth material at 1% (w/w) per samples was found to be the most appropriate sorbent and the amount of sorbed pigments was calculated as 1.01x10–4 mmol/g ads. for chlorophyll, 1.15x10–3 mmol/g ads. for carotene and 1.70 red on Lovibond colour scale. The procedure indicated that this system can be easily adapted to the actual oil refi ning systems.

Słowa kluczowe

Wydawca

-

Rocznik

Tom

63

Numer

3

Opis fizyczny

p.147-154,fig.,ref.

Twórcy

autor
  • Selcuk University, Faculty of Science, Department of Chemistry, 42075 Campus, Konya, Turkey
  • Seluk University, Faculty of Science, Department of Chemistry, 42075 Campus, Konya, Turkey
autor
  • Karamanoglu Mehmetbey University, Faculty of Science, Department of Chemistry, 70010 Campus, Karaman, Turkey
  • Selcuk University, Faculty of Science, Department of Chemistry, 42075 Campus, Konya, Turkey
autor
  • Selcuk University, Faculty of Science, Department of Chemistry, 42075 Campus, Konya, Turkey
autor
  • Helvacizade Edible Oil Company, Konya, Turkey
autor
  • Konya Necmettin Erbakan University, Faculty of Science, Department of Biotechnology, Konya, Turkey

Bibliografia

  • 1. Achife E.C., Ibemesi J.A., Applicability of the Freundlich and Langmuir adsorption isotherms in the bleaching of rubber and melon seed oils. J. Am. Chem. Soc., 1989, 66, 247–252.
  • 2. Ahmaruzzaman M., Sharma D.K., Adsorption of phenols from wastewater. J. Colloid Interf. Sci., 2005, 287, 14–24.
  • 3. Alfa Laval Separation AB, Methods for Analysis Application General Manual MA 0901. Alfa Laval Separation AB, 1995, Tumba, Sweden.
  • 4. AOCS, Offi cial Methods and Recommended Practices of the American Oil Chemists’ Society. 1998, 4th edition, Champaign, IL: AOCS Press.
  • 5. Arslan F.N., Increasing of Usage Effi ciencies Of Cottonseed Oils Produced in Our Country by Improving Their Refi nery Process. 2009, M. Sc. Thesis. Selçuk University Institute of the Natural and Applied Sciences, Turkey.
  • 6. Boukerroui A., Oualı M.S., Edible oil bleaching with a bentonite activated by microwave irradiation. Ann. Chim.-Sci. Mat., 2002, 27, 73–81.
  • 7. Diaz F.R.V., Santoz P.S., Studies on the acid activation of Brazilian smectitic clays. Quim Nova, 2001, 24, 345–353.
  • 8. Didi M.A., Makhoukhi B., Azzouz A., Villemin D., Colza oil bleaching through optimized acid activation of bentonite. A comparative study. Appl. Clay Sci., 2009, 42, 336–344.
  • 9. Erten Y., Use of Domestic Minerals for Vegetable Oil Bleaching. 2004, Master Thesis, İzmir Institute of Technology, İzmir, Turkey
  • 10. Gezici O., Kara H., Ersoz M., Abali Y., The sorption behavior of a nickel-insolubilized humic acid system in a column arrangement. J. Colloid Interf. Sci., 2005, 292, 381–391.
  • 11. Gezici O., Kara H., Ayar A., Topkafa M., Sorption behavior of Cu(II) ions on insolubilized humic acid under acidic conditions: An application of Scatchard plot analysis in evaluating the pH dependence of specific and nonspecific bindings. Sep. Purif. Technol., 2007, 55, 132–139.
  • 12. Helferrich F., Ion Exchange, 1962, McGraw-Hill, New York.
  • 13. Ho Y.S., Porter J.F., McKay G., Equilibrium isotherm studies for the sorption of divalent metal ions onto peat: Copper, nickel and lead single component systems. Water Air Soil Poll., 2002, 141, 1–33.
  • 14. Hymore F.K., Effects of some additives on the performance of acid-activated clays in the bleaching of palm oil. Appl. Clay Sci., 1996, 10, 379–385.
  • 15. Kara H., Ayyildiz H.F., Topkafa M., Use of aminoprophyl silicaimmobilized humic acid for Cu(II) ions removal from aqueous solution by using a continuously monitored solid phase extraction technique in a column arrangement. Colloid Surface A, 2008, 312, 62–72.
  • 16. Kaynak G., Ersoz M., Kara H., Investigation of the properties of oil at the bleaching unit of an oil refinery. J. Colloid Interf. Sci., 2004, 280, 131–138
  • 17. Langmuir I., The constitution and fundamental properties of solids and liquids. Part I. Solids. J. Am. Chem. Soc., 1916, 38, 2221–2295.
  • 18. Ozdere G., Kurt G., Mercimek B., Ayar A., Ligand adsorption of adenine and adenosine on poly(vinyl chloride) bound cobalt(II)–carboxylated diaminoethyl complex. Colloid Surface A, 2003, 223, 287–293.
  • 19. Reddy K.K., Subramanian R., Kawakatsu T., Nakajima M., Decolorization of vegetable oils by membrane processing. Eur. Food Res. Technol., 2001, 213, 212–218.
  • 20. Rey F., Calle E., Casado J., Study of the effects of concentration and pH on the dissociation kinetics of Fe(II)-fulvic acid complexes. Int. J. Chem. Kinet., 1997, 30, 63–67.
  • 21. Rossi M., Gianazza M., Alamprese C., Stanga F., The role of bleaching clays and synthetic silica in palm oil physical refining. Food Chem., 2003, 82, 291–296.
  • 22. Tor A., Cengeloglu Y., Aydin M.E., Ersoz M., Removal of phenol from aqueous phase by using neutralized red mud. J. Colloid Interf. Sci., 2006, 300, 498–503.
  • 23. Zschau W., Bleaching of edible fats and oils. Eur. J. Lipid Sci. Tech., 2001, 103, 505–508.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

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