Optimization of corrosion inhibition of Picralima nitida leaves extract as green corrosion inhibitor for zinc in 1.0 M HCl

• Autorzy: Ezeugo J.N.O. , Onukwuli O.D. , Omotioma M.
• Języki publikacji: EN

Abstrakty

EN

Herein, the optimization of inhibitive action of the ethanol extract of oil from Picralima nitida leaves, towards acid corrosion of zinc, was tested using weight loss and thermometry methods. We found that the extract acts as a good corrosion inhibitor for zinc corrosion in 0.1 M HCl solutions. The inhibition action of the extract was discussed in view of Langmuir adsorption isotherm. This revealed that spontaneous processes govern the adsorption of the extract on zinc surface. Herein, the inhibition efficiency (IE) increases in line with corresponding increase in extract concentration. The temperature effect of the corrosion inhibition on the IE was also studied. This indicated that the presence of the extract increases the needed activation energy of the corrosion reaction. Furthermore, in our work, an optimal inhibition efficiency IE (%) of 86.78 was obtained at optimum inhibitor concentration of 1.2 gl-1, optimum temperature and time of 313 k and 8 hrs, respectively. From the calculated thermodynamic parameters, it can be said, then, that Picralima nitida extract provides good protection to zinc against pitting corrosion in chloride ion containing solutions.

• Wydawca: -
• Czasopismo: World News of Natural Sciences
• Rocznik: 2017
• Tom: 15
• Opis fizyczny: p.139-161,fig.,ref.

Twórcy

autor

Ezeugo J.N.O.

• Department of Chemical Engineering, Chukwuemeka Odumegwu Ojukwu University, Anambra State, Nigeria

autor

Onukwuli O.D.

• Department of Chemical Engineering, Nnamdi Azikiwe University, Awka, Nigeria

autor

Omotioma M.

• Department of Chemical Engineering, Enugu State University of Science and Technology, Enugu, Nigeria

Bibliografia

• [1] I. Radojčić, K. Berković, S. Kovač, J. Vorkapić-Furač, Corros. Sci 50 (2008) 1498-1504, https://doi.org/10.1016/j.corsci.2008.01.013
• [2] Khadom, A.A. Yaro, A.S. Altaie, A.A.H. Kadum, Portug. Electrochim. Acta 27 (6) (2009) 699-712
• [3] A.K. Satapathy, G. Gunasekaran, S.C. Sahoo, K. Amit, P.V. Rodrigues, Corros. Sci. 51 (2009) 2848-2856
• [4] A.Y. El-Etre, Corros. Sci. 45 (2003) 2485-2495
• [5] B. Valdez, J. Cheng, F. Flores, M. Schorr, L. Veleva. Corrosion Rev. 21 (2003) 445-458
• [6] E.E. Oguzie, Pigment. Resin. Tech. 35 (2006) 334-340
• [7] E.M. Mabrouk, H. Shoky, K.M. Abu Al-Naja, Chem. Met. Alloys 4 (2011) 98-106
• [8] I.J. Alinno, P.M. Ejikeme, America Chem. Sci. J. 2 (2012) 122-135
• [9] J. Anuradha, R. Vimala, B. Narayanasanly, S. Arochia, D.S. Rajendran, Lenn. Chem. Eng. Comm. 195 (2008) 352-366.
• [10] J.T. Nwabanne, V.N. Okafor, J. Emer. Trends. In Engin. And App. Sci. 2 (2011) 619-625
• [11] K.F. Khaled. Int. J. Electrochem. Sci. 3 (2008) 462-475
• [12] K.O. Rubite-Okorosaye, N.C. Oforka, J. Appl. Sci. Environ. Mgt. 8 (2004) 57-61
• [13] L. Octave, Chemical Reaction Engineering, 3rd eds. John Wily and Sons, New York, 2003.
• [14] L.A. Nnanna, I.O. Owate, O.C. Nwadiuko, N.D., Ekekowe, W.J. Oji, Int. J. Mater. Chem. 3 (2013) 10-16
• [15] M. Lebrini, M. Traisnel, M. Lagrenee, B. Mernari, F. Bentiss, Corros. Sci. 50 (2008) 473-479
• [16] Mesbah, C. Juers, Lacouture, F. Mathieu, S. Rocca, E. Francois, J. Steinmetz, J. Solid State. Sci 9 (2007) 322-328
• [17] N. Nagm, N.G. Kandile, E.A. Bad R, M.A. Mohammd, Corros. Sci 65 (2012) 94-103
• [18] N.G. Thompson, M. Yunovich, D. Don mire, Corrosion Rev. 25 (2007) 247-262
• [19] N.O. Eddy, B.I. Ita, S.N. Dodo, E.D. Paul, Green Chem. Lett. Rev. 5 (2012). 43 – 53.
• [20] N.S. Patel, S. Jauhariand, G.N. Melita, S.S. Al-Deyeb, I. Warad, B. Hammouti, Int. J. Electrochem. Sci. 8 (2013) 2635-2655
• [21] P.C. Okafor, V.I. Osabor, E.E. Ebenso, Pig. Res. Technol. 36 (2007) 299-305
• [22] P.L. Cabot, F.A. Centellas, J.A. Garrido, E. Perez, H. Vidal, Electrochem. Acta 36 (1991) 179
• [23] P.R. Bothi, M.G. Sethuraman, Mater Lett. 62 (2008) 113-116
• [24] S. Rajendran, A.J. Amalraj, M.J. Joice, N. Anthony, D.C. Trevedi, M. Sundaravadivelu, Corrs. Rev. 22 (2004) 233-248
• [25] S.A. Umoren, E.E. Ebenso, Mater Chem. Phys. 106 (2007) 393
• [26] S.A.M. Refeay, A.E. Malak, A.M. Taha, F. Abdel-Fatah, H.T.M. Int. J. Electrochm. Sci. 3 (2008) 167-176
• [27] S.K. Sharma, A. Mudhoo, G. Jain, E. Khamisa. Green Chem. Lett. Rev. 2 (2009) 47-51
• [28] S.R. Taylor, B.D. Chambers, Corros. Rev. 25 (2007) 571-590
• [29] X. Li, S. Deng, Corros. Sci. 65 (2012) 299-308
• [30] E. Rodriquez-clemente, J.G. Gonzalez-Rodriguez and M.G. Valladares-Cisneros, Int. J. Electrochem. Sci. 9 (2014) 5924-5936
• [31] Espinoza-vazquez, G.E. Negron-Silva, D. Angeles-Beltran., H. Herrera-Hernandez, M. Romero-Romo, M. Palomar-Par dave. Int. J. Electrochem. Sci. 9 (2014) 493-509
• [32] S. Abd El-Aziz Fouda, Ahmed Abdel Nazeer, Y. Ayman El-Khateeb, and Mohamed Fakih. J. of the Korean Chemical Society 58 (2014) 359-365
• [33] Krzysztof Rokosz, Tadeusz Hryniewicz. World Scientific News 35 (2016) 44-61
• [34] Krzysztof Rokosz, Tadeusz Hryniewicz. World Scientific News 37 (2016) 232-248
• [35] Krzysztof Rokosz, Tadeusz Hryniewicz, Patrick Chapon, Łukasz Dudek. World Scientific News 57 (2016) 289-299
• [36] F. E. Abeng, V. D. Idim, O. E. Obono, T. O. Magu, World Scientific News 77(2) (2017) 298-313
• [37] Krzysztof Rokosz, Tadeusz Hryniewicz, Kornel Pietrzak, Łukasz Dudek, Winfried Malorny. World Scientific News 70(2) (2017) 71-85